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Preparation of mesoporous carbon materials used in electrochemical capacitor electrode by using natural zeolite template/maltose system
Luo, Heming; Zhang, Fengbo; Zhao, Xia; Sun, Yanxia; Du, Kaifa; Feng, Huixia
刊名JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
2014-01
卷号25期号:1页码:538-545
关键词Capacitance Carbon Crystallinity Cyclic voltammetry Field emission microscopes High resolution transmission electron microscopy Lamellar structures Mesoporous materials Scanning electron microscopy Zeolites Absorption/desorption Electrochemical capacitor Electrochemical impedance spectra Electrochemical measurements Field emission scanning electron microscopy Mesoporous carbon materials Property characterizations Specific capacitance
ISSN号0957-4522
DOI10.1007/s10854-013-1621-4
英文摘要Mesoporous carbons (NZMC) were synthesized by using single-step nanocasting in which maltose was used as carbon precursors and natural zeolite as template. Physical property characterization methods such as field emission scanning electron microscopy, transmission electron microscopy, N-2 absorption/desorption, and X-ray diffraction were employed to determine the structure and crystallinity of NZMC. The results show that the materials possess a disordered lamellar structure and numerous nanopores. The specific surface area and pore volume reach up to 1076.9 m(2)/g and 1.46 cm(3)/g, respectively. Typical electrochemical measurements such as constant current charge/discharge test, cyclic voltammetry (CV), and electrochemical impedance spectra revealed that NZMC has excellent charge storage capability. Specific capacitance is 176 F/g in the alkaline media when the current density is 600 mA/g. The CV curve maintains a typical CV quasi-rectangular feature at a scan rate of 5-100 mV/s, which indicates that the materials perform well rate capability. The combination resistance of the carbon materials is 0.78 Omega. After 750 cycles, the specific capacitance retention value is 94.5 %, which proves that NZMC is a promising electrode material for electrochemical capacitors because of its long-term cycle stability.
资助项目National Natural Science Foundation of China[NSFC.51063003] ; College Students Training Project for Creative and Entrepreneurship of China[1210731150]
WOS研究方向Engineering ; Materials Science ; Physics
语种英语
出版者SPRINGER
WOS记录号WOS:000329233600075
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/34507]  
专题石油化工学院
教务处(创新创业学院)
通讯作者Feng, Huixia
作者单位Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Gansu, Peoples R China
推荐引用方式
GB/T 7714
Luo, Heming,Zhang, Fengbo,Zhao, Xia,et al. Preparation of mesoporous carbon materials used in electrochemical capacitor electrode by using natural zeolite template/maltose system[J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,2014,25(1):538-545.
APA Luo, Heming,Zhang, Fengbo,Zhao, Xia,Sun, Yanxia,Du, Kaifa,&Feng, Huixia.(2014).Preparation of mesoporous carbon materials used in electrochemical capacitor electrode by using natural zeolite template/maltose system.JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,25(1),538-545.
MLA Luo, Heming,et al."Preparation of mesoporous carbon materials used in electrochemical capacitor electrode by using natural zeolite template/maltose system".JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS 25.1(2014):538-545.
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