Preparation of mesoporous carbon materials used in electrochemical capacitor electrode by using natural zeolite template/maltose system | |
Luo, Heming; Zhang, Fengbo; Zhao, Xia; Sun, Yanxia; Du, Kaifa; Feng, Huixia | |
刊名 | JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
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2014-01 | |
卷号 | 25期号:1页码:538-545 |
关键词 | Capacitance Carbon Crystallinity Cyclic voltammetry Field emission microscopes High resolution transmission electron microscopy Lamellar structures Mesoporous materials Scanning electron microscopy Zeolites Absorption/desorption Electrochemical capacitor Electrochemical impedance spectra Electrochemical measurements Field emission scanning electron microscopy Mesoporous carbon materials Property characterizations Specific capacitance |
ISSN号 | 0957-4522 |
DOI | 10.1007/s10854-013-1621-4 |
英文摘要 | Mesoporous carbons (NZMC) were synthesized by using single-step nanocasting in which maltose was used as carbon precursors and natural zeolite as template. Physical property characterization methods such as field emission scanning electron microscopy, transmission electron microscopy, N-2 absorption/desorption, and X-ray diffraction were employed to determine the structure and crystallinity of NZMC. The results show that the materials possess a disordered lamellar structure and numerous nanopores. The specific surface area and pore volume reach up to 1076.9 m(2)/g and 1.46 cm(3)/g, respectively. Typical electrochemical measurements such as constant current charge/discharge test, cyclic voltammetry (CV), and electrochemical impedance spectra revealed that NZMC has excellent charge storage capability. Specific capacitance is 176 F/g in the alkaline media when the current density is 600 mA/g. The CV curve maintains a typical CV quasi-rectangular feature at a scan rate of 5-100 mV/s, which indicates that the materials perform well rate capability. The combination resistance of the carbon materials is 0.78 Omega. After 750 cycles, the specific capacitance retention value is 94.5 %, which proves that NZMC is a promising electrode material for electrochemical capacitors because of its long-term cycle stability. |
资助项目 | National Natural Science Foundation of China[NSFC.51063003] ; College Students Training Project for Creative and Entrepreneurship of China[1210731150] |
WOS研究方向 | Engineering ; Materials Science ; Physics |
语种 | 英语 |
出版者 | SPRINGER |
WOS记录号 | WOS:000329233600075 |
状态 | 已发表 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.223/handle/2XXMBERH/34507] ![]() |
专题 | 石油化工学院 教务处(创新创业学院) |
通讯作者 | Feng, Huixia |
作者单位 | Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Gansu, Peoples R China |
推荐引用方式 GB/T 7714 | Luo, Heming,Zhang, Fengbo,Zhao, Xia,et al. Preparation of mesoporous carbon materials used in electrochemical capacitor electrode by using natural zeolite template/maltose system[J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,2014,25(1):538-545. |
APA | Luo, Heming,Zhang, Fengbo,Zhao, Xia,Sun, Yanxia,Du, Kaifa,&Feng, Huixia.(2014).Preparation of mesoporous carbon materials used in electrochemical capacitor electrode by using natural zeolite template/maltose system.JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS,25(1),538-545. |
MLA | Luo, Heming,et al."Preparation of mesoporous carbon materials used in electrochemical capacitor electrode by using natural zeolite template/maltose system".JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS 25.1(2014):538-545. |
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