Metal–Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal–Sulfur Batteries

doi:10.1002/adma.202008784

	Metal–Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal–Sulfur Batteries
	Yan, Rui 2; Ma, Tian 2; Cheng, Menghao 2; Tao, Xuefeng 2; Yang, Zhao 3; Ran, Fen 3; Li, Shuang 1; Yin, Bo 2; Cheng, Chong 2,4; Yang, Wei 2
刊名	Advanced Materials
	2021-07-08
卷号	33 期号:27
关键词	Charge transfer Electric batteries Energy storage Metal-Organic Frameworks Metals Nanostructures Organic polymers Organometallics Sulfur Topography Catalytic conversion Critical challenges Electrochemical performance Energy storage systems Future generations High surface area Metalorganic frameworks (MOFs) Topography controls
ISSN号	09359648
DOI	10.1002/adma.202008784
英文摘要	Metal-sulfur batteries (MSBs) are considered up-and-coming future-generation energy storage systems because of their prominent theoretical energy density. However, the practical applications of MSBs are still hampered by several critical challenges, i.e., the shuttle effects, sluggish redox kinetics, and low conductivity of sulfur species. Recently, benefiting from the high surface area, regulated networks, molecular/atomic-level reactive sites, the metal-organic frameworks (MOFs)-derived nanostructures have emerged as efficient and durable multifaceted electrodes in MSBs. Herein, a timely review is presented on recent advancements in designing MOF-derived electrodes, including fabricating strategies, composition management, topography control, and electrochemical performance assessment. Particularly, the inherent charge transfer, intrinsic polysulfide immobilization, and catalytic conversion on designing and engineering of MOF nanostructures for efficient MSBs are systematically discussed. In the end, the essence of how MOFs’ nanostructures influence their electrochemical properties in MSBs and conclude the future tendencies regarding the construction of MOF-derived electrodes in MSBs is exposed. It is believed that this progress review will provide significant experimental/theoretical guidance in designing and understanding the MOF-derived nanostructures as multifaceted electrodes, thus offering promising orientations for the future development of fast-kinetic and robust MSBs in broad energy fields. © 2021 The Authors. Advanced Materials published by Wiley-VCH GmbH
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种	英语
出版者	John Wiley and Sons Inc
WOS记录号	WOS:000653589400001
内容类型	期刊论文
源URL	[http://ir.lut.edu.cn/handle/2XXMBERH/151132]
专题	材料科学与工程学院
作者单位	1.Functional Materials, Department of Chemistry, Technische Universität Berlin, Hardenbergstraße 40, Berlin; 10623, Germany; 2.College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Department of Ultrasound, West China Hospital, Sichuan University, Chengdu; 610065, China; 3.State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou; Gansu; 730050, China; 4.Department of Chemistry and Biochemistry, Freie Universität Berlin, Takustrasse 3, Berlin; 14195, Germany
推荐引用方式 GB/T 7714	Yan, Rui,Ma, Tian,Cheng, Menghao,et al. Metal–Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal–Sulfur Batteries[J]. Advanced Materials,2021,33(27).
APA	Yan, Rui.,Ma, Tian.,Cheng, Menghao.,Tao, Xuefeng.,Yang, Zhao.,...&Yang, Wei.(2021).Metal–Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal–Sulfur Batteries.Advanced Materials,33(27).
MLA	Yan, Rui,et al."Metal–Organic-Framework-Derived Nanostructures as Multifaceted Electrodes in Metal–Sulfur Batteries".Advanced Materials 33.27(2021).