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Facile synthesis of WS2/Ni3S2 encapsulated in N-doped carbon hybrid electrode with high rate performance as anode for sodium-ion batteries
Duan, Mingtao1; Meng, Yanshuang1,3; Xiao, Mingjun1; Ahmed, Wail Hafiz Zaki1; Wang, Xin1; Gao, Hongfu1; Zhang, Yue2; Zhu, Fuliang1,3
刊名JOURNAL OF ELECTROANALYTICAL CHEMISTRY
2021-10-15
卷号899
关键词WS2/Ni3S2 Hybrid electrode High rate performance Sodium-ion batteries
ISSN号1572-6657
DOI10.1016/j.jelechem.2021.115681
英文摘要The sodium ion batteries (SIBs) are a promising candidate for large-scale energy storage owing to the abundance and low cost of sodium resources. However, the absence of suitable anode materials with desired rate capability and cycle stability is one of the bottlenecks for their commercialization. In this work, WS2/Ni3S2@N-doped carbon composite (WS2/Ni3S2@NC) was prepared by using a simple solvothermal approach with subsequent annealing approach. The material was used as anode material for SIBs. The batteries showed excellent performance due to the special bimetallic sulfide heterostructure, which could provide reaction active sites, promote fast Na ions diffusion, and increase electrode/electrolyte contact. In addition, the in-situ synthesized N-doped carbon layer could effectively improve the electronic conductivity as well as maintain structural stability. As anode of SIBs, the WS2/Ni3S2@NC exhibits both excellent rate performance (329.6 mAh g(-1) at 0.1 A g(-1), and 129.6 mAh g(-1) at 5.0 A g(-1)) and outstanding cycling stability (219.7 mAh g(-1) after 80 cycles at 0.1 A g(-1)) due to the pseudocapacitive behavior.
WOS研究方向Chemistry ; Electrochemistry
语种英语
出版者ELSEVIER SCIENCE SA
WOS记录号WOS:000696964200001
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/148940]  
专题材料科学与工程学院
作者单位1.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Peoples R China;
2.Georgia Southern Univ, Dept Mfg Engn, Statesboro, GA 30458 USA;
3.State Key Lab Adv Proc & Recycling Non Ferrous Me, Lanzhou 730050, Peoples R China
推荐引用方式
GB/T 7714
Duan, Mingtao,Meng, Yanshuang,Xiao, Mingjun,et al. Facile synthesis of WS2/Ni3S2 encapsulated in N-doped carbon hybrid electrode with high rate performance as anode for sodium-ion batteries[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,2021,899.
APA Duan, Mingtao.,Meng, Yanshuang.,Xiao, Mingjun.,Ahmed, Wail Hafiz Zaki.,Wang, Xin.,...&Zhu, Fuliang.(2021).Facile synthesis of WS2/Ni3S2 encapsulated in N-doped carbon hybrid electrode with high rate performance as anode for sodium-ion batteries.JOURNAL OF ELECTROANALYTICAL CHEMISTRY,899.
MLA Duan, Mingtao,et al."Facile synthesis of WS2/Ni3S2 encapsulated in N-doped carbon hybrid electrode with high rate performance as anode for sodium-ion batteries".JOURNAL OF ELECTROANALYTICAL CHEMISTRY 899(2021).
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