Selective identification and separation of ReO4- by biomimetic flexible temperature-sensitive imprinted composite membranes | |
Zhao, Shengyuan1,2; Wang, Runtian1,2; Ou, Xiaojian3; Zhang, Jun1,2; Li, Hui1,2; Liu, Chunli1,2; Chen, Zhengcan1,2; Zhang, Xiaoyan1,2; Huo, Ting1,2; Chen, Zhenbin1,2 | |
刊名 | TALANTA |
2021-12-01 | |
卷号 | 235 |
关键词 | Imprinted composite membrane Temperature-sensitive Selective separation ReO4- |
ISSN号 | 0039-9140 |
DOI | 10.1016/j.talanta.2021.122791 |
英文摘要 | A new type of temperature-sensitive imprinted composite membranes(ICMs) was developed. Poly N,N-diethylacrylamide (DEA) blocks, as temperature-sensitive polymer, were grafted onto the substrate of the imprinted polymer separation layer to endow membranes with better adsorption effect. The comprehensive properties of the imprinted composite membranes were adequately tested and evaluated in detail. Results showed that ReO4--ICMs (Re-ICMs) with temperature-sensitive recognition sites could adjust the structure of the imprinted holes at different temperatures, which presented excellent performance in the selective separation and purification of ReO4-. The prepared Re-ICMs exhibit the maximum adsorption capacity of 0.1639 mmol/g at 35 degrees C with the equilibrium adsorption time of 2 h. After ten adsorption/desorption cycles, Re-ICMs could still maintain 73.5% of the original adsorption capacity, the separation degree of ReO4-/MnO4- was only reduced from the initial 24.5 to 15.9, and the desorption ratio dropped from 80.4% to 68.4%, indicating that Re-ICMs have excellent adsorption and separation performance and reusability. |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | ELSEVIER |
WOS记录号 | WOS:000701202700001 |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/148746] |
专题 | 材料科学与工程学院 |
作者单位 | 1.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China; 2.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China; 3.State Key Lab Nickel & Cobalt Resources Comprehen, Jinchang 737100, Gansu, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Shengyuan,Wang, Runtian,Ou, Xiaojian,et al. Selective identification and separation of ReO4- by biomimetic flexible temperature-sensitive imprinted composite membranes[J]. TALANTA,2021,235. |
APA | Zhao, Shengyuan.,Wang, Runtian.,Ou, Xiaojian.,Zhang, Jun.,Li, Hui.,...&Zhang, Peng.(2021).Selective identification and separation of ReO4- by biomimetic flexible temperature-sensitive imprinted composite membranes.TALANTA,235. |
MLA | Zhao, Shengyuan,et al."Selective identification and separation of ReO4- by biomimetic flexible temperature-sensitive imprinted composite membranes".TALANTA 235(2021). |
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