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Nanoengineering of transparent polypropylene containing sorbitol-based clarifier
Liu, Xiaoting3,4; Liu, Xin3,4; Li, Yanqin5; Zhang, Yunfei3,4; Xie, Xin5; Li, Ke3,4; Chen, Zhenbin3,4; Zhang, Liji5; Tang, Zhenghua1,6; Liu, Zhen2
刊名Journal of Polymer Research
2020-08-01
卷号27期号:8
关键词Clarifiers Crystallization Differential scanning calorimetry Light scattering Polypropylenes Scanning electron microscopy Structural properties Transparency Condensed structures Crystallization behavior Crystallization properties Dynamic thermomechanical analysis Injection pressures Low injection pressure Morphological changes Oriented structure
ISSN号10229760
DOI10.1007/s10965-020-02169-3
英文摘要

In this work, 1,2,3-trideoxy-4,6:5,7-bis-O-[(4-propylphenyl) methylene]-nonitol (TBPMN) was conscripted as the clarifying agent, the influence of the injection pressure on optical properties of PP were investigated, and results documented that increasing the injection pressure could not improve the transparency of the transparent PP. Thereafter, the crystallization behavior and morphological changes of transparent PP in condensed structure under different injection pressures were studied by the differential scanning calorimetry (DSC), the scanning electron microscopy (SEM) and the dynamic thermomechanical analysis (DMA), respectively, and results presented that change in injection pressure influence crystallization properties significantly. Besed on analyzing of the relationship between structure and optical properties, the effect of pressure on the optical properties was explained as follows: low injection pressure would be facilitated to the transparency of transparent PP, because under low injection pressure, the clarifier fiber could be dispersed uniformly and the network structure was formed and preserved well, and molecular chains of transparent PP was crystallized to the nanometer-level fiber on the surface of nucleation sites, which greatly reduces the scattering of light. However, increasing the injection pressure would promote the fiber itself accumulation into a scatterer point, which not only reduces the effect of the clarifier, but also causes the preferential arrangement of the PP molecules to produce an oriented structure due to strong external force and shearing action, thereby increasing light scattering. © 2020, The Polymer Society, Taipei.

WOS研究方向Polymer Science
语种英语
出版者Springer
WOS记录号WOS:000550003700001
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/115520]  
专题材料科学与工程学院
作者单位1.Guangzhou Key Laboratory for Surface Chemistry of Energy Materials, New Energy Research Institute, School of Environment and Energy, Guangzhou Higher Education Mega Centre, South China University of Technology, Guangzhou; 5100067, China;
2.Department of Physics and Engineering, Frostburg State University, Frostburg; MD; 21532, United States
3.State Key Laboratory of Gansu AdvancedNon-ferrous Metal Materials, Lanzhou University of Technology, Lanzhou; Gansu; 730050, China;
4.School of Material Science and Engineering, Lanzhou University of Technology, Lanzhou; Gansu; 730050, China;
5.PetroChina Lanzhou Petrochemical Research Center, PetroChina, Lanzhou; Gansu; 730060, China;
6.Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, Guangdong Provincial Engineering and Technology Research Center for Environmental Risk Prevention and Emergency Disposal, School of Environment and Energy, Guangzhou Higher Education Mega Centre, South China University of Technology, Guangzhou; 510006, China;
推荐引用方式
GB/T 7714
Liu, Xiaoting,Liu, Xin,Li, Yanqin,et al. Nanoengineering of transparent polypropylene containing sorbitol-based clarifier[J]. Journal of Polymer Research,2020,27(8).
APA Liu, Xiaoting.,Liu, Xin.,Li, Yanqin.,Zhang, Yunfei.,Xie, Xin.,...&Liu, Zhen.(2020).Nanoengineering of transparent polypropylene containing sorbitol-based clarifier.Journal of Polymer Research,27(8).
MLA Liu, Xiaoting,et al."Nanoengineering of transparent polypropylene containing sorbitol-based clarifier".Journal of Polymer Research 27.8(2020).
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