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Microporous carbon nanofibers prepared by combining electrospinning and phase separation methods for supercapacitor
Liu, Chang1; Tan, Yongtao1; Liu, Ying1; Shen, Kuiwen1; Peng, Bowu1; Niu, Xiaoqin1; Ran, Fen1,2
刊名JOURNAL OF ENERGY CHEMISTRY
2016-07
卷号25期号:4页码:587-593
关键词Supercapacitor Electrospinning Nanofiber Phase separation
ISSN号2095-4956
DOI10.1016/j.jechem.2016.03.017
英文摘要Microporous carbon nanofibers (MCNFs) derived from polyacrylonitrile nanofibers were fabricated via electrospinning technology and phase separation in the presence of polyvinylpyrrolidone (PVP). PVP together with a mixed solvent of N, N-Dimethylformamide and dimethyl sulfoxide was used as pore forming agent. The influences of PVP content in casting solution on the structure and electrochemical performance of the MCNFs were also investigated. The highest capacitance of 200 F/g was obtained on a three-electrode system at a scan rate of 0.5 A/g. The good performance was owing to the high specific surface area and the large amount of micro-pores, which enhanced the absorption and the transportation efficiency of electrolyte ion during charge/discharge process. This research indicated that the combination of electrospinning and phase separation technology could be used to fabricate microporous carbon nanofibers as electrode materials for supercapacitors with high specific surface area and outstanding electrochemical performance. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
资助项目National Natural Science Foundation of China[51203071][51363014][51362018] ; China Postdoctoral Science Foundation[2014M552509] ; Opening Project of State Key Laboratory of Polymer Materials Engineering (Sichuan University)[sklpme2014-4-25] ; Program for Hongliu Distinguished Young Scholars in Lanzhou University of Technology[J201402] ; University Scientific Research Project of Gansu Province[2014B-025]
WOS研究方向Chemistry ; Energy & Fuels ; Engineering
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000388913300005
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/33654]  
专题材料科学与工程学院
省部共建有色金属先进加工与再利用国家重点实验室
通讯作者Ran, Fen
作者单位1.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China
2.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China
推荐引用方式
GB/T 7714
Liu, Chang,Tan, Yongtao,Liu, Ying,et al. Microporous carbon nanofibers prepared by combining electrospinning and phase separation methods for supercapacitor[J]. JOURNAL OF ENERGY CHEMISTRY,2016,25(4):587-593.
APA Liu, Chang.,Tan, Yongtao.,Liu, Ying.,Shen, Kuiwen.,Peng, Bowu.,...&Ran, Fen.(2016).Microporous carbon nanofibers prepared by combining electrospinning and phase separation methods for supercapacitor.JOURNAL OF ENERGY CHEMISTRY,25(4),587-593.
MLA Liu, Chang,et al."Microporous carbon nanofibers prepared by combining electrospinning and phase separation methods for supercapacitor".JOURNAL OF ENERGY CHEMISTRY 25.4(2016):587-593.
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