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Preparation of Co3O4/Carbon Derived from Ionic Liquid and Its Application in Lithium-ion Batteries
Wang, Gongrui1; Zhu, Fuliang1,3; Xia, Jun1; Wang, Lei1; Meng, Yanshuang1; Zhang, Yue2
刊名ELECTROCHIMICA ACTA
2017-12-10
卷号257页码:138-145
关键词lithium-ion batteries Co3O4/C composite ionic liquid derived carbon
ISSN号0013-4686
DOI10.1016/j.electacta.2017.10.077
英文摘要In this paper, we report an ionic liquid derived Co3O4/Carbon (Co3O4/C) material synthesized by a carbothermic reduction followed by a low-temperature oxidation, which is certified by XRD and TEM. The as-synthesized Co3O4/C composite has a uniform structure with well-crystalized Co3O4 embedded in carbon matrix (onion-like carbon materials). The carbon held tightly on the Co3O4 particles can prevent the disintegration of Co3O4/C composite during cycling and, therefore, improve the integrity of the composite. Moreover, the carbon component of the composite can enhance the dynamic characteristic of the Co3O4/C composite, which can accelerate the electronic conductivity. The composite delivers excellent lithium storage performances with outstanding cycling performance (868 and 877 mAh g(-1) after 200 cycles at a current density of 89 mAh g(-1)) and admirable rate capability (660 and 669 mAh g(-1) at a rate of 2C) in lithium-ion batteries (LIBs), showing great prospect as electrode material for LIBs. (C) 2017 Elsevier Ltd. All rights reserved.
资助项目Foundation for Innovation Groups of Basic Research in Gansu Province[1606RJIA322]
WOS研究方向Electrochemistry
语种英语
出版者PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号WOS:000414067900016
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/32974]  
专题材料科学与工程学院
通讯作者Zhu, Fuliang; Zhang, Yue
作者单位1.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China
2.Texas A&M Univ Kingsville, Dept Mech & Ind Engn, Kingsville, TX 78363 USA
3.State Key Lab Adv Proc & Recycling Nonferrous Me, Lanzhou 730050, Gansu, Peoples R China
推荐引用方式
GB/T 7714
Wang, Gongrui,Zhu, Fuliang,Xia, Jun,et al. Preparation of Co3O4/Carbon Derived from Ionic Liquid and Its Application in Lithium-ion Batteries[J]. ELECTROCHIMICA ACTA,2017,257:138-145.
APA Wang, Gongrui,Zhu, Fuliang,Xia, Jun,Wang, Lei,Meng, Yanshuang,&Zhang, Yue.(2017).Preparation of Co3O4/Carbon Derived from Ionic Liquid and Its Application in Lithium-ion Batteries.ELECTROCHIMICA ACTA,257,138-145.
MLA Wang, Gongrui,et al."Preparation of Co3O4/Carbon Derived from Ionic Liquid and Its Application in Lithium-ion Batteries".ELECTROCHIMICA ACTA 257(2017):138-145.
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