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In situ coating on LiFePO4 with ionic liquid as carbon source for high-performance lithium batteries
Xia, Jun1; Zhu, Fuliang1,2; Wang, Lei1; Wang, Gongrui1; Meng, Yanshuang1,2; Zhang, Yue3
刊名JOURNAL OF NANOPARTICLE RESEARCH
2018-07-17
卷号20期号:7
关键词In situ coating Ionic liquid Lithium ion batteries LiFePO4 Electrochemistry Energy storage
ISSN号1388-0764
DOI10.1007/s11051-018-4298-z
英文摘要LiFePO4/C materials were synthesized via an in situ coating on LiFePO4 with 1-butyl-3-methylimidazolium dicyanamide [BMIm][N(CN)(2)] as a carbon source. The electrode materials were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectra, Raman spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results revealed that 1-2 nm carbon films were successfully coated on the LiFePO4 particles. The electrochemical properties of LiFePO4/C composite were investigated by cyclic voltammetry (CV) curves, electrochemical impedance spectra (EIS), and electrochemical analysis. The test results showed that the LiFePO4/C composite possessed outstanding reversibility, cycle performance, and rate performance. The discharge capacities of LiFePO4/C were 161.5 mAh g(-1) at 0.1 C and 143.6 mAh g(-1) at 1 C, respectively. The excellent electrochemical properties of the LiFePO4/C electrode were mainly due to the thin, uniform, and highly graphitized carbon films.
资助项目Foundation for Innovation Groups of Basic Research in Gansu Province[1606RJIA322]
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
语种英语
出版者SPRINGER
WOS记录号WOS:000439528100001
状态已发表
内容类型期刊论文
源URL[http://119.78.100.223/handle/2XXMBERH/32555]  
专题材料科学与工程学院
通讯作者Meng, Yanshuang; Zhang, Yue
作者单位1.Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China
2.State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China
3.Georgia Southern Univ, Dept Mfg Engn, Statesboro, GA 30460 USA
推荐引用方式
GB/T 7714
Xia, Jun,Zhu, Fuliang,Wang, Lei,et al. In situ coating on LiFePO4 with ionic liquid as carbon source for high-performance lithium batteries[J]. JOURNAL OF NANOPARTICLE RESEARCH,2018,20(7).
APA Xia, Jun,Zhu, Fuliang,Wang, Lei,Wang, Gongrui,Meng, Yanshuang,&Zhang, Yue.(2018).In situ coating on LiFePO4 with ionic liquid as carbon source for high-performance lithium batteries.JOURNAL OF NANOPARTICLE RESEARCH,20(7).
MLA Xia, Jun,et al."In situ coating on LiFePO4 with ionic liquid as carbon source for high-performance lithium batteries".JOURNAL OF NANOPARTICLE RESEARCH 20.7(2018).
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