Underliquid Superlyophobic Copper-Coated Meshes for the Separation of Immiscible Organic Liquid Mixtures | |
Zhao, Zhihong1,3; Shen, Yongqian2; Yang, Haidong1; Li, Jian1; Guo, Lin3 | |
刊名 | ACS APPLIED MATERIALS & INTERFACES
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2019-08-07 | |
卷号 | 11期号:31页码:28370-28376 |
关键词 | electrodeposition copper-coated mesh hierarchical rough structure underliquid superlyophobicity organic liquid mixture separation |
ISSN号 | 1944-8244 |
DOI | 10.1021/acsami.9b05812 |
英文摘要 | Superwettable materials have been studied extensively and successfully applied in various forms liquid separation. However, because of low surface tension differences, organic liquids (OLs) exhibit approximate wettability on most of the material surfaces, and the separation of OL mixtures remains a challenge. The current separation method for OL mixtures is mainly dependent on covalent modification to precisely control the surface energy of the membranes, which is extremely complicated. Herein, we demonstrate a novel concept of underliquid super-lyophobicity for the separation of immiscible OLs mixtures, which only depend on a relatively stable liquid-repellent interface. Furthermore, the minimum system's free-energy principle was used to explain this wetting behavior. Different from the previous reports, the method of separation of OL mixtures does not involve various low-surface-energy materials, thus it is facile and eco-friendly. Our research provides a general strategy for the efficient separation of immiscible OLs mixtures and is expected to promote the development of superwettable materials for multiphase liquid separation. |
资助项目 | Yong Teacher Research Group Foundation of Northwest Normal University[NWNU-LKQN-16-6] |
WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000480498600096 |
状态 | 已发表 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.223/handle/2XXMBERH/31650] ![]() |
专题 | 材料科学与工程学院 |
通讯作者 | Li, Jian |
作者单位 | 1.Northwest Normal Univ, Coll Chem & Chem Engn, Res Ctr Gansu Mil & Civilian Integrat Adv Struct, Lanzhou 730070, Peoples R China 2.Lanzhou Univ Technol, Sch Mat Sci & Engn, Key Lab Nonferrous Met Alloys & Proc, Minist Educ,State Key Lab Adv Proc & Recycling No, Lanzhou 730050, Gansu, Peoples R China 3.Beihang Univ, Sch Chem, Key Lab Bioinspired Smart Interfacial Sci & Techn, Beijing 100191, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Zhihong,Shen, Yongqian,Yang, Haidong,et al. Underliquid Superlyophobic Copper-Coated Meshes for the Separation of Immiscible Organic Liquid Mixtures[J]. ACS APPLIED MATERIALS & INTERFACES,2019,11(31):28370-28376. |
APA | Zhao, Zhihong,Shen, Yongqian,Yang, Haidong,Li, Jian,&Guo, Lin.(2019).Underliquid Superlyophobic Copper-Coated Meshes for the Separation of Immiscible Organic Liquid Mixtures.ACS APPLIED MATERIALS & INTERFACES,11(31),28370-28376. |
MLA | Zhao, Zhihong,et al."Underliquid Superlyophobic Copper-Coated Meshes for the Separation of Immiscible Organic Liquid Mixtures".ACS APPLIED MATERIALS & INTERFACES 11.31(2019):28370-28376. |
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