Fabrication of 3D Porous Polyvinyl Alcohol/Sodium Alginate/Graphene Oxide Spherical Composites for the Adsorption of Methylene Blue | |
Ma, Ying-Xia1; Li, Xin1; Shao, Wen-Jie1; Kou, Ya-Lan1; Yang, Hai-Peng2; Zhang, Ding-Jun1 | |
刊名 | JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY |
2020-04 | |
卷号 | 20期号:4页码:2205-2213 |
关键词 | Polyvinyl Alcohol Sodium Alginate Graphene Oxide Adsorption Methylene Blue |
ISSN号 | 1533-4880 |
DOI | 10.1166/jnn.2020.17193 |
英文摘要 | In this study, three-dimensional (3D) networked porous polyvinyl alcohol/sodium alginate/graphene oxide (PVA/SA/GO) spherical composites were fabricated by the sol gel method and employed as adsorbents for the adsorption of methylene blue (MB) in aqueous solution. The obtained samples were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermal property analysis, and nitrogen adsorption/desorption isotherms. Moreover, the adsorption properties for MB were investigated by batch experiments. The pseudo-first-order and pseudo-second-order equations were used to fit the adsorption kinetics data, and the Langmuir and Freundlich isothermal models were used to analyze the adsorption isothermals. The results showed that the spherical composites had 3D porous structures, and GO, PVA and SA were fused and linked together by self-assembly, physical intertwining, hydrogen bonding, and Ca2+ and boric acid crosslinking. The maximum adsorption capacity of the 3D porous PVA/SA/GO spherical composites for MB was 759.3 mg/g. The adsorption kinetics had a better agreement with the pseudo-second order equation than the pseudo-first-order equation, and the equilibrium data followed the Freundlich model. |
资助项目 | opening foundation of Guangdong Research Center for Interfacial Engineering of Functional Materials, College of Materials Science and Engineering, Shenzhen University[G1701] |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
语种 | 英语 |
出版者 | AMER SCIENTIFIC PUBLISHERS |
WOS记录号 | WOS:000484789100025 |
状态 | 已发表 |
内容类型 | 期刊论文 |
源URL | [http://119.78.100.223/handle/2XXMBERH/31467] |
专题 | 材料科学与工程学院 |
通讯作者 | Ma, Ying-Xia |
作者单位 | 1.Lanzhou Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China 2.Shenzhen Univ, Coll Mat Sci & Engn, Guangdong Res Ctr Interfacial Engn Funct Mat, Shenzhen 518060, Peoples R China |
推荐引用方式 GB/T 7714 | Ma, Ying-Xia,Li, Xin,Shao, Wen-Jie,et al. Fabrication of 3D Porous Polyvinyl Alcohol/Sodium Alginate/Graphene Oxide Spherical Composites for the Adsorption of Methylene Blue[J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2020,20(4):2205-2213. |
APA | Ma, Ying-Xia,Li, Xin,Shao, Wen-Jie,Kou, Ya-Lan,Yang, Hai-Peng,&Zhang, Ding-Jun.(2020).Fabrication of 3D Porous Polyvinyl Alcohol/Sodium Alginate/Graphene Oxide Spherical Composites for the Adsorption of Methylene Blue.JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,20(4),2205-2213. |
MLA | Ma, Ying-Xia,et al."Fabrication of 3D Porous Polyvinyl Alcohol/Sodium Alginate/Graphene Oxide Spherical Composites for the Adsorption of Methylene Blue".JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 20.4(2020):2205-2213. |
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