Destructive effects of transitional metal ions on interfacial film of carbon anode for lithium-ion batteries | |
J., Zhang; W., Li; J., Wang; P., Wang; J., Sun; S., Wu; H., Dong; H., Ding; D., Zhao; S., Li | |
刊名 | Electrochimica Acta |
2022-06-10 | |
卷号 | 417 |
关键词 | Anodes Carbon Metal ions Seebeck effect Solid electrolytes Transition metal compounds Transition metals Capacity degradation Carbon anodes Destructive effects Electrochemical performance Electrode material Interfacial film Lithium salts Solid electrolyte interface films Transition metal ions Transitional metal ions |
ISSN号 | 0013-4686 |
DOI | 10.1016/j.electacta.2022.140334 |
英文摘要 | The dissolution, migration, and deposition of transition metal (TM) ions are the main reasons for the capacity degradation of lithium-ion batteries, which significantly affect their comprehensive electrochemical performance and safety. In this work, the effects of different TM ions (Mn2+, Co2+, and Ni2+) on the electrochemical performance of lithium/mesocarbon microbeads half-cell were compared, and the mechanism was discussed. It is found that Mn2+ ions inhibit the decomposition of lithium salt and promote the decomposition of solvents, resulting in the crack of electrode material and solid electrolyte interface (SEI) film and the increase of capacity degradation. In contrast, Ni2+ ions promote the decomposition of lithium salts to a certain extent, thus inhibiting the excessive damage to the SEI film and electrode material. This study can provide theoretical support and research direction for the design of the electrolytes that can alleviate the damage of TM ions to the anode and the SEI film. © 2022 Elsevier Ltd |
WOS研究方向 | Electrochemistry |
语种 | 英语 |
出版者 | Elsevier Ltd |
WOS记录号 | WOS:000806493700003 |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/158383] |
专题 | 兰州理工大学 |
作者单位 | 1.Gansu Engineering Laboratory of Cathode Material for Lithium-ion Battery, Baiyin; 730050, China 2.School of Petrochemical Technology, Lanzhou University of Technology, Lanzhou; 730050, China; 3.Key Laboratory of Low Carbon Energy and Chemical Engineering of Gansu Province, Lanzhou; 730050, China; |
推荐引用方式 GB/T 7714 | J., Zhang,W., Li,J., Wang,et al. Destructive effects of transitional metal ions on interfacial film of carbon anode for lithium-ion batteries[J]. Electrochimica Acta,2022,417. |
APA | J., Zhang.,W., Li.,J., Wang.,P., Wang.,J., Sun.,...&S., Li.(2022).Destructive effects of transitional metal ions on interfacial film of carbon anode for lithium-ion batteries.Electrochimica Acta,417. |
MLA | J., Zhang,et al."Destructive effects of transitional metal ions on interfacial film of carbon anode for lithium-ion batteries".Electrochimica Acta 417(2022). |
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