Growth and Electrochemical Behavior of Poly[Ni(saldMp)] on Carbon Nanotubes as Potential Supercapacitor Materials

CORC > 过程工程研究所 > 中国科学院过程工程研究所 > 多相复杂系统国家重点实验室

	Growth and Electrochemical Behavior of Poly[Ni(saldMp)] on Carbon Nanotubes as Potential Supercapacitor Materials
	Zhang, Yakun 1; Li, Jianling 1; Kang, Feiyu 2; Wang, Xindong 1; Ye, Feng 3; Yang, Jun 3
刊名	BULLETIN OF THE KOREAN CHEMICAL SOCIETY
	2012-06-20
卷号	33 期号:6 页码:1972-1978
关键词	Redox polymer Poly[Ni(saldMp)] Electrochemical polymerization Supercapacitor
ISSN号	0253-2964
通讯作者	Li, JL
英文摘要	The polymer of (2,2-dimethyl-1,3-propanediaminebis(salicylideneaminato))-nickel(II), Ni(saldMp), was deposited on multi-walled carbon nanotubes (MWCNTs) substrate by the route of potential linear sweep. The nano structures of poly[Ni(saldMp)] have been obtained by adjusting the monomer concentration of 0.1, 0.2, 0.5, 1.0 and 1.5 mmol L-1. The poly[Ni(saldMp)] prepared in acetonitrile solution with monomer concentration of 1.0 mmol L-1 shows the fastest growth rate. The effects of potential window on charge-discharge efficiency and electrodeposition scan number on capacitance performance were discussed. Poly[Ni(saldMp)] prepared with less electrodeposition scans exhibits higher capacitance, but this goes against the improvement of the whole electrode capacitance. Sample with 8 deposition scans is the best compromise with the geometric specific capacitance 3.53 times as high as that of pure MWCNTs, and 1.24 times for the gravimetric specific capacitance under the test potential window 0.0-1.0 V.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Multidisciplinary
研究领域[WOS]	Chemistry
关键词[WOS]	CAPACITIVE ENERGY-STORAGE ; DOUBLE-LAYER CAPACITORS ; MODIFIED ELECTRODES ; POLYMER ; COMPOSITE ; MNO2 ; POLYPYRROLE ; DESIGN ; REDOX ; FILMS
收录类别	SCI
语种	英语
WOS记录号	WOS:000305667400032
公开日期	2013-10-16
内容类型	期刊论文
版本	出版稿
源URL	[http://ir.ipe.ac.cn/handle/122111/3575]
专题	过程工程研究所_多相复杂系统国家重点实验室
作者单位	1.Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China 2.Tsinghua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Yakun,Li, Jianling,Kang, Feiyu,et al. Growth and Electrochemical Behavior of Poly[Ni(saldMp)] on Carbon Nanotubes as Potential Supercapacitor Materials[J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY,2012,33(6):1972-1978.
APA	Zhang, Yakun,Li, Jianling,Kang, Feiyu,Wang, Xindong,Ye, Feng,&Yang, Jun.(2012).Growth and Electrochemical Behavior of Poly[Ni(saldMp)] on Carbon Nanotubes as Potential Supercapacitor Materials.BULLETIN OF THE KOREAN CHEMICAL SOCIETY,33(6),1972-1978.
MLA	Zhang, Yakun,et al."Growth and Electrochemical Behavior of Poly[Ni(saldMp)] on Carbon Nanotubes as Potential Supercapacitor Materials".BULLETIN OF THE KOREAN CHEMICAL SOCIETY 33.6(2012):1972-1978.