Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9
	Zhou Lin; Pan Shilie; Su Xin; Yang Zhihua; Wu Hongping; Yu Hongwei; Zhang Fangfang; Cui Sifang; Zhou Zhongxiang
刊名	JOURNAL OF MOLECULAR STRUCTURE
	2013
卷号	1049 期号:10 页码:473-478
关键词	KPbB5O9 Synthesis Crystal structure Theoretical calculations
ISSN号	0022-2860
通讯作者	Pan, SL
中文摘要	A new potassium lead pentaborate compound, KPbB5O9 has been synthesized by standard solid-state reaction for the first time. Its structure has been determined by single-crystal X-ray diffraction method. It crystallizes in the monoclinic space group P2(1)/c with lattice constants a = 6.717(3) angstrom, b = 8.389(3) angstrom, c = 13.686(5) angstrom, beta = 94.679(4)degrees and Z = 4. The structure consists of double ring B5O9 units, KO8 and PbO6 polyhedra. The PbO6 polyhedra linked together via corner-sharing O atom forming novel infinite (infinity)PbO6 chains along the b axis. Thermal analyses, IR spectroscopy and UV-vis-NIR diffuse reflectance spectrum, and band structure calculation were performed.
学科主题	Chemistry
收录类别	SCI
资助信息	973 Program of China 2012CB626803; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of CAS KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of CAS; Funds for Creative Cross & Cooperation Teams of CAS, Major Program of Xinjiang Uygur Autonomous Region of China during the 12th Five-Year Plan Period 201130111; High Technology Research & Development Program of Xinjiang Uygur Autonomous Region of China 201116143; Science and Technology Project of Urumqi G121130002
公开日期	2013-11-07
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/2631]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, CAS, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100039, Peoples R China;Huazhong Univ Sci & Technol, Sch Opt & Elect Informat, Wuhan 430074, Peoples R China
推荐引用方式 GB/T 7714	Zhou Lin,Pan Shilie,Su Xin,et al. Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9[J]. JOURNAL OF MOLECULAR STRUCTURE,2013,1049(10):473-478.
APA	Zhou Lin.,Pan Shilie.,Su Xin.,Yang Zhihua.,Wu Hongping.,...&Zhou Zhongxiang.(2013).Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9.JOURNAL OF MOLECULAR STRUCTURE,1049(10),473-478.
MLA	Zhou Lin,et al."Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9".JOURNAL OF MOLECULAR STRUCTURE 1049.10(2013):473-478.