Synthesis, structure and characterization of layered Ca[B(C6H6O7)(2)](H2O)(4)center dot HCl

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	Synthesis, structure and characterization of layered Ca[B(C6H6O7)(2)](H2O)(4)center dot HCl
	Wu Hongping; Pan Shilie; Yu Hongwei; Huang Zhenjun; Jia Dianzeng
刊名	JOURNAL OF MOLECULAR STRUCTURE
	2012
卷号	1027 期号:11 页码:111-115
关键词	CaB(C6H6O7)(2)(H2O)(4)center dot HCl Crystal structure Crystal growth Inorganic-organic borate
ISSN号	0022-2860
通讯作者	Pan, SL
中文摘要	Introduction of the citric acid in the borate system generates a new phase. CaB(C6H6O7)(2)(H2O)(4)center dot HCl, which is transparent from 195 nm to near infrared region. Single crystals of CaB(C6H6O7)(2)(H2O)(4)center dot HCl with dimensions up to 7 x 5 x 2 mm(3) were successfully grown by slow evaporation method at room temperature. It has been characterized by single crystal X-ray diffraction, infrared spectroscopy measure and thermogravimetric analysis. CaB(C6H6O7)(2)(H2O)(4)center dot HCl crystallizes in the triclinic space group P - 1, with a = 6.3243(18) angstrom, b = 8.365(2) angstrom, c = 19.042(5) angstrom, alpha = 97.291(3)degrees, beta = 94.535(4)degrees, gamma = 94.165(4)degrees. It exhibits a unique layered structure, the layers are parallel arrangement of the (001) plane and stack along the c-axis.
学科主题	Chemistry
收录类别	SCI
资助信息	Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-209-3, KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114, 21065012; "One Hundred Talents Project Foundation Program" of Chinese Academy of Sciences; "Western Light Joint Scholar Foundation" Program of Chinese Academy of Sciences; "High Technology Research and Development Program" of Xinjiang Uygur Autonomous Region of China 201116143; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211B33, 200821166; Scientific Research Program of Urumqi of China G09212001; Science and Technology in Support of Xinjiang 201091244
公开日期	2013-11-07
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/2749]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
推荐引用方式 GB/T 7714	Wu Hongping,Pan Shilie,Yu Hongwei,et al. Synthesis, structure and characterization of layered Ca[B(C6H6O7)(2)](H2O)(4)center dot HCl[J]. JOURNAL OF MOLECULAR STRUCTURE,2012,1027(11):111-115.
APA	Wu Hongping,Pan Shilie,Yu Hongwei,Huang Zhenjun,&Jia Dianzeng.(2012).Synthesis, structure and characterization of layered Ca[B(C6H6O7)(2)](H2O)(4)center dot HCl.JOURNAL OF MOLECULAR STRUCTURE,1027(11),111-115.
MLA	Wu Hongping,et al."Synthesis, structure and characterization of layered Ca[B(C6H6O7)(2)](H2O)(4)center dot HCl".JOURNAL OF MOLECULAR STRUCTURE 1027.11(2012):111-115.