Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 新疆维吾尔自治区电子信息材料与器件重点实验室

	Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units
	Zhou Lin; Pan Shilie; Dong Xiaoyu; Yu Hongwei; Wu Hongping; Zhang Fangfang; Zhou Zhongxiang
刊名	CRYSTENGCOMM
	2013
卷号	15 期号:17 页码:3412-3416
ISSN号	1466-8033
中文摘要	A new noncentrosymmetric compound, Na2Cd7B8O20, has been synthesized by solid-state reaction for the first time. The crystal structure has been determined from single crystal X-ray diffraction data. The compound crystallizes in the orthorhombic space group Fdd2 with a = 51.5597(7) angstrom, b = 58.6920(8) angstrom and c = 3.381 angstrom. The crystal structure is composed of CdOn (n = 6, 7), Na-CdOn (n = 5, 6) NaOn (n = 4, 6) polyhedra, B3O7 and BO3 units. The B3O7 unit is built up of three BO3 groups via corner-sharing, rarely found in borate compounds. The IR spectrum, the optical diffuse reflectance spectrum and nonlinear optical properties of Na2Cd7B8O20 are reported.
学科主题	Chemistry ; Crystallography
收录类别	SCI
资助信息	National Natural Science Foundation of China U1129301, 51172277, 21201176, 50802110, 21101167, 21101168, 11104344; Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-H03-03; "One Hundred Talents Project Foundation Program" of Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; "High Technology Research and Development Program" of Xinjiang Uygur Autonomous Region of China 201116143
公开日期	2013-11-07
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/2694]
专题	新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhou Lin,Pan Shilie,Dong Xiaoyu,et al. Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units[J]. CRYSTENGCOMM,2013,15(17):3412-3416.
APA	Zhou Lin.,Pan Shilie.,Dong Xiaoyu.,Yu Hongwei.,Wu Hongping.,...&Zhou Zhongxiang.(2013).Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units.CRYSTENGCOMM,15(17),3412-3416.
MLA	Zhou Lin,et al."Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units".CRYSTENGCOMM 15.17(2013):3412-3416.