Fluorination of alpha-Fe2O3 by NH4HF2 to Produce FeF3 | |
Wang, Hong1,3; Zhou, Yuebo1,3; Mo, Chenggang1,3; Zhang, Lina1,3; Cui, Junjun2 | |
刊名 | RUSSIAN JOURNAL OF INORGANIC CHEMISTRY |
2021-12-01 | |
卷号 | 66期号:14页码:2017-2026 |
关键词 | ammonium bifluoride fluorination thermal decomposition FeF3 derivative thermogravimetry differential thermal analysis |
ISSN号 | 0036-0236 |
DOI | 10.1134/S0036023621140060 |
通讯作者 | Wang, Hong(54729951@qq.com) |
英文摘要 | Fluorination of alpha-Fe2O3 by NH4HF2 has been analyzed in this study using simultaneous thermogravimetry and differential thermal analysis (TG-DTA), scanning electron microscopy (SEM), and X-ray powder diffraction (XRD). The results indicated that the mass ratio NH4HF2 to Fe2O3 has no influence on the fluorination process. The fluorination starts at room temperature, dominates at 175.6 degrees C, and completes at 200 degrees C with the formation of (NH4)(3)FeF6. With further heat-treatment, (NH4)(3)FeF6 progressively releases NH4F by the formation of NH4FeF4 at 258.1 degrees C, then (NH4)(0.18)FeF3 at 320 degrees C and finally FeF3 with minor FeF2 at 400 degrees C. NH4F released during the decomposition of (NH4)(3)FeF6 will fluorinate the un-reacted Fe2O3. |
资助项目 | Scientific Research Fund of Liaoning Provincial Education Department[L202002] |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | MAIK NAUKA/INTERPERIODICA/SPRINGER |
WOS记录号 | WOS:000740986600002 |
资助机构 | Scientific Research Fund of Liaoning Provincial Education Department |
内容类型 | 期刊论文 |
源URL | [http://ir.imr.ac.cn/handle/321006/173747] |
专题 | 金属研究所_中国科学院金属研究所 |
通讯作者 | Wang, Hong |
作者单位 | 1.Shenyang Inst Technol, Sch Mech Engn & Automat, Fushun 113122, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 3.Shenyang Inst Technol, Liaoning Key Lab Informat Phys Fus & Intelligent, Fushun 113122, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Hong,Zhou, Yuebo,Mo, Chenggang,et al. Fluorination of alpha-Fe2O3 by NH4HF2 to Produce FeF3[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,2021,66(14):2017-2026. |
APA | Wang, Hong,Zhou, Yuebo,Mo, Chenggang,Zhang, Lina,&Cui, Junjun.(2021).Fluorination of alpha-Fe2O3 by NH4HF2 to Produce FeF3.RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,66(14),2017-2026. |
MLA | Wang, Hong,et al."Fluorination of alpha-Fe2O3 by NH4HF2 to Produce FeF3".RUSSIAN JOURNAL OF INORGANIC CHEMISTRY 66.14(2021):2017-2026. |
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