FeCl3-functionalized graphene oxide/single-wall carbon nanotube/silicon heterojunction solar cells with an efficiency of 17.5%

doi:10.1039/d2ta00217e

CORC > 金属研究所 > 中国科学院金属研究所

	FeCl3-functionalized graphene oxide/single-wall carbon nanotube/silicon heterojunction solar cells with an efficiency of 17.5%
	Hu, Xian-Gang 1,2; Wei, Qinwei 1,2; Zhao, Yi-Ming 1,2; Hou, Peng-Xiang 1,2; Ren, Wencai 1,2; Liu, Chang 1,2; Cheng, Hui-Ming 1,3
刊名	JOURNAL OF MATERIALS CHEMISTRY A
	2022-02-03
页码	9
ISSN号	2050-7488
DOI	10.1039/d2ta00217e
通讯作者	Hou, Peng-Xiang(pxhou@imr.ac.cn) ; Liu, Chang(cliu@imr.ac.cn)
英文摘要	Single-wall carbon nanotube/silicon (SWCNT/Si) heterojunction solar cells are no longer a laboratory curiosity, but the commercial manufacture of devices with a high and stable conversion efficiency remains a big challenge. Here we report the fabrication of a FeCl3-functionalized GO/SWCNT/Si heterojunction solar cell by using a simple drop-casting method. It was found that the GO layer not only serves as an antireflection layer, leading to reduced incident light loss and a similar to 20% increase in photocurrent, but also acts as a carrier transport bridge and physical barrier that traps more metal chloride. The FeCl3 acts as a solid-state redox functional material doping both the GO and the SWCNT film, resulting in a higher-conductivity composite film, which increases the work function and the charge carrier transport, contributing to a significant increase of the photovoltage and fill factor. As a result, the FeCl3-GO/SWCNT/Si heterojunction solar cell achieved a high conversion efficiency of 17.5% and good stability, where more than 90% of original efficiency was retained after exposure to air for 15 days.
资助项目	Ministry of Science and Technology of China[2016YFA0200102] ; National Natural Science Foundation of China[51761135122] ; National Natural Science Foundation of China[51532008] ; National Natural Science Foundation of China[51625203] ; National Natural Science Foundation of China[51772303] ; National Natural Science Foundation of China[51872293] ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Liaoning BaiQianWan Talents Program
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000750991500001
资助机构	Ministry of Science and Technology of China ; National Natural Science Foundation of China ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Liaoning BaiQianWan Talents Program
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/173582]
专题	金属研究所_中国科学院金属研究所
通讯作者	Hou, Peng-Xiang; Liu, Chang
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 2.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 3.Tsinghua Univ, Shenzhen Geim Graphene Ctr, Shenzhen Int Grad Sch, Shenzhen 518055, Peoples R China
推荐引用方式 GB/T 7714	Hu, Xian-Gang,Wei, Qinwei,Zhao, Yi-Ming,et al. FeCl3-functionalized graphene oxide/single-wall carbon nanotube/silicon heterojunction solar cells with an efficiency of 17.5%[J]. JOURNAL OF MATERIALS CHEMISTRY A,2022:9.
APA	Hu, Xian-Gang.,Wei, Qinwei.,Zhao, Yi-Ming.,Hou, Peng-Xiang.,Ren, Wencai.,...&Cheng, Hui-Ming.(2022).FeCl3-functionalized graphene oxide/single-wall carbon nanotube/silicon heterojunction solar cells with an efficiency of 17.5%.JOURNAL OF MATERIALS CHEMISTRY A,9.
MLA	Hu, Xian-Gang,et al."FeCl3-functionalized graphene oxide/single-wall carbon nanotube/silicon heterojunction solar cells with an efficiency of 17.5%".JOURNAL OF MATERIALS CHEMISTRY A (2022):9.