Facile synthesis of N, P co-doped carbon encapsulated Ni catalyst for green production of cyclopentanone from biomass derivative furfural

doi:10.1016/j.fuel.2022.123815

	Facile synthesis of N, P co-doped carbon encapsulated Ni catalyst for green production of cyclopentanone from biomass derivative furfural
	Hu, Zhi 1,2; Xie, Aidi 2; Chen, Chun 1,2; Zou, Zidan 1,2; Shen, Yue 1,2; Fu, Zhen 1; Zhang, Yunxia 1,2; Zhang, Haimin 1,2; Zhao, Huijun 1,3; Wang, Guozhong 1,2
刊名	FUEL
	2022-07-01
卷号	319
关键词	N, P co-doped Ionic liquid Hydrogenation Rearrangement Nickel
ISSN号	0016-2361
DOI	10.1016/j.fuel.2022.123815
通讯作者	Chen, Chun(chenchun2013@issp.ac.cn) ; Wang, Guozhong(gzhwang@issp.ac.cn)
英文摘要	Aqueous-phase hydrogenation-rearrangement tandem (AP-HRT) reaction is a green and sustainable route to produce cyclopentanone from bio-based furan compounds. Herein, the ionic liquid was applied as the precursor to synthesize Ni@NP-C catalyst, which contains high dispersed nickel nanoparticles (Ni NPs) encapsulated in the N, P co-doped carbon layer, for the selectivity transformation of furfural towards cyclopentanone. The synthesized Ni@NP-C catalyst can afford 100% FAL conversion and 86.7% CPO yield at 130 degrees C and 1.5 MPa H-2 within 2 h AP-HRT reaction. The introduction of the electronegative heteroatom on the surface can not only improve the adsorption of reactant but also provide weak Lewis Acid sites for being beneficial to the high selectivity of cyclopentanone. The catalyst displays superior activity, selectivity, and stability in the tandem catalytic system in view of the tunable chemical states of the doped heteroatoms by handily adjusting the pyrolysis temperature.
资助项目	National Natural Science Foundation of China[51871209] ; National Natural Science Foundation of China[52072371] ; Key Technologies Research and Development Program of Anhui Province[202004a06020056] ; Special Foundation of President of HFIPS[YZJJ202102]
WOS关键词	HYDROGENATIVE RING-REARRANGEMENT ; CHEMOSELECTIVE HYDROGENATION ; NANOPARTICLES ; CONVERSION ; EFFICIENT
WOS研究方向	Energy & Fuels ; Engineering
语种	英语
出版者	ELSEVIER SCI LTD
WOS记录号	WOS:000783223300002
资助机构	National Natural Science Foundation of China ; Key Technologies Research and Development Program of Anhui Province ; Special Foundation of President of HFIPS
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/128561]
专题	中国科学院合肥物质科学研究院
通讯作者	Chen, Chun; Wang, Guozhong
作者单位	1.Chinese Acad Sci, Inst Solid State Phys, Ctr Environm & Energy Nanomat, Key Lab Mat Phys,HFIPS, Hefei 230031, Peoples R China 2.Univ Sci & Technol China, Hefei 230026, Peoples R China 3.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Brisbane, Qld 4222, Australia
推荐引用方式 GB/T 7714	Hu, Zhi,Xie, Aidi,Chen, Chun,et al. Facile synthesis of N, P co-doped carbon encapsulated Ni catalyst for green production of cyclopentanone from biomass derivative furfural[J]. FUEL,2022,319.
APA	Hu, Zhi.,Xie, Aidi.,Chen, Chun.,Zou, Zidan.,Shen, Yue.,...&Wang, Guozhong.(2022).Facile synthesis of N, P co-doped carbon encapsulated Ni catalyst for green production of cyclopentanone from biomass derivative furfural.FUEL,319.
MLA	Hu, Zhi,et al."Facile synthesis of N, P co-doped carbon encapsulated Ni catalyst for green production of cyclopentanone from biomass derivative furfural".FUEL 319(2022).