Partial Phosphorization: A Strategy to Improve Some Performance(s) of Thiolated Metal Nanoclusters Without Notable Reduction of Stability

doi:10.1002/chem.202200212

	Partial Phosphorization: A Strategy to Improve Some Performance(s) of Thiolated Metal Nanoclusters Without Notable Reduction of Stability
	He, Zongbing 1,2; Yang, Ying 1,2; Zou, Jiafeng 1,2; You, Qing 1,2; Feng, Lei 1,2; Li, Man-Bo 1,2; Wu, Zhikun 1,2
刊名	CHEMISTRY-A EUROPEAN JOURNAL
	2022-03-25
关键词	catalysis partial phosphorization photoluminescence thiolated gold nanocluster
ISSN号	0947-6539
DOI	10.1002/chem.202200212
通讯作者	Li, Man-Bo(mbli@ahu.edu.cn) ; Wu, Zhikun(zkwu@issp.ac.cn)
英文摘要	Thiolates endow metal nanoclusters with stability while sometimes inhibit the catalytic activity due to the strong M-S interaction (M: metal atom). To improve the catalytic activity and keep the stability to some extent, one strategy is the partial phosphorization of thiolated metal nanoclusters. This is demonstrated by successful partial phosphorization of Au-23(SC6H11)(16) and by revealing that the products Au-22(SC6H11)(14)(PPh3)(2) and Au-22(SC6H11)(12)(PPh3)(4), with varied degree of phosphorization, both show excellent activity in the photocatalytic oxidation of thioanisole without notable reduction of stability. Furthermore, Au-22(SC6H11)(12)(PPh3)(4) exhibits better photoluminescence performance than the mother nanocluster Au-23(SC6H11)(16), indicating that partial phosphorization can also improve some other performance(s) except for the catalytic performance. The intermediates Au22-xCux(SC6H11)(12)(PPh3)(4) (x=1, 2) in the transformation from Au-23(SC6H11)(16) (Au-22(SC6H11)(14)(PPh3)(2)) to Au-22(SC6H11)(12)(PPh3)(4) were captured and identified by mass spectrometry and single crystal X-ray diffraction, which throws light on the understanding of the non-alloyed anti-galvanic reaction.
资助项目	National Natural Science Foundation of China[92061110] ; National Natural Science Foundation of China[21829501] ; National Natural Science Foundation of China[21925303] ; National Natural Science Foundation of China[21771186] ; National Natural Science Foundation of China[21222301] ; National Natural Science Foundation of China[21171170] ; National Natural Science Foundation of China[21528303] ; CASHIPS Director's Fund[BJPY2019A02] ; Key Program of the 13th five year plan, CASHIPS[KP-2017-16] ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology[2020HSC-CIP005] ; Anhui Provincial Natural Science Foundation[2108085Y05] ; Hefei National Laboratory for Physical Sciences at the Microscale[KF2020102]
WOS关键词	ANTI-GALVANIC REDUCTION ; GOLD NANOCLUSTERS ; PROTECTED GOLD ; CRYSTAL-STRUCTURE ; OXIDATION ; CORE ; NANOPARTICLES ; AU-15 ; TRANSFORMATION ; LUMINESCENT
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000772906400001
资助机构	National Natural Science Foundation of China ; CASHIPS Director's Fund ; Key Program of the 13th five year plan, CASHIPS ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Anhui Provincial Natural Science Foundation ; Hefei National Laboratory for Physical Sciences at the Microscale
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/128219]
专题	中国科学院合肥物质科学研究院
通讯作者	Li, Man-Bo; Wu, Zhikun
作者单位	1.Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Anhui, Peoples R China 2.Chinese Acad Sci, Anhui Key Lab Nanomat & Nanotechnol, CAS Ctr Excellence Nanosci, Inst Solid State Phys,HFIPS,Key Lab Mat Phys, Hefei 230031, Peoples R China
推荐引用方式 GB/T 7714	He, Zongbing,Yang, Ying,Zou, Jiafeng,et al. Partial Phosphorization: A Strategy to Improve Some Performance(s) of Thiolated Metal Nanoclusters Without Notable Reduction of Stability[J]. CHEMISTRY-A EUROPEAN JOURNAL,2022.
APA	He, Zongbing.,Yang, Ying.,Zou, Jiafeng.,You, Qing.,Feng, Lei.,...&Wu, Zhikun.(2022).Partial Phosphorization: A Strategy to Improve Some Performance(s) of Thiolated Metal Nanoclusters Without Notable Reduction of Stability.CHEMISTRY-A EUROPEAN JOURNAL.
MLA	He, Zongbing,et al."Partial Phosphorization: A Strategy to Improve Some Performance(s) of Thiolated Metal Nanoclusters Without Notable Reduction of Stability".CHEMISTRY-A EUROPEAN JOURNAL (2022).