Competitive exchange between divalent metal ions [Cu(II), Zn(II), Ca(II)] and Hg(II) bound to thiols and natural organic matter

doi:10.1016/j.jhazmat.2021.127388

CORC > 青海盐湖研究所 > 中国科学院青海盐湖研究所 > 盐湖资源与化学实验室

	Competitive exchange between divalent metal ions [Cu(II), Zn(II), Ca(II)] and Hg(II) bound to thiols and natural organic matter
	Zhang, Yaoling; Zhang, Lijie; Liang, Xujun; Wang, Quanying; Yin, Xiangping; Pierce, Eric M.; Gu, Baohua
刊名	JOURNAL OF HAZARDOUS MATERIALS
	2021-10
卷号	424
ISSN号	0304-3894
DOI	10.1016/j.jhazmat.2021.127388
英文摘要	Mercuric Hg(II) ion forms exceptionally strong complexes with various organic ligands, particularly thiols and dissolved organic matter (DOM) in natural water. Few studies, however, have experimentally determined whether or not the presence of base cations and transition metal ions, such as Ca(II), Cu(II), and Zn(II), would compete with Hg(II) bound to these ligands, as concentrations of these metal ions are usually orders of magnitude higher than Hg(II) in aquatic systems. Different from previous model predictions, a significant fraction of Hg(II) bound to cysteine (CYS), glutathione (GSH), or DOM was found to be competitively exchanged by Cu(II), but not by Zn(II) or Ca(II). About 20-75% of CYS-bound-Hg(II) [at 2:1 CYS:Hg(II)] and 14-40% of GSH-bound-Hg(II) [at 1:1 GSH:Hg(II)] were exchanged by Cu(II) at concentrations 1-3 orders of magnitude greater than Hg(II). Competitive exchange was also observed between Cu(II) and Hg(II) bound to DOM, albeit to a lower extent, depending on relative abundances of thiol and carboxylate functional groups on DOM and their equilibrium time with Hg(II). When complexed with ethylenediaminetetraacetate (EDTA), most Hg(II) could be exchanged by Cu(II) and Zn(II), as well as Ca(II) at increasing concentrations. These results shed additional light on competitive exchange reactions between Hg(II) and coexisting metal ions and have important implications in Hg(II) chemical speciation and biogeochemical transformation, particularly in contaminated environments containing relatively high concentrations of Hg(II) and metal ions.
内容类型	期刊论文
源URL	[http://ir.isl.ac.cn/handle/363002/34578]
专题	青海盐湖研究所_盐湖资源与化学实验室
推荐引用方式 GB/T 7714	Zhang, Yaoling,Zhang, Lijie,Liang, Xujun,et al. Competitive exchange between divalent metal ions [Cu(II), Zn(II), Ca(II)] and Hg(II) bound to thiols and natural organic matter[J]. JOURNAL OF HAZARDOUS MATERIALS,2021,424.
APA	Zhang, Yaoling.,Zhang, Lijie.,Liang, Xujun.,Wang, Quanying.,Yin, Xiangping.,...&Gu, Baohua.(2021).Competitive exchange between divalent metal ions [Cu(II), Zn(II), Ca(II)] and Hg(II) bound to thiols and natural organic matter.JOURNAL OF HAZARDOUS MATERIALS,424.
MLA	Zhang, Yaoling,et al."Competitive exchange between divalent metal ions [Cu(II), Zn(II), Ca(II)] and Hg(II) bound to thiols and natural organic matter".JOURNAL OF HAZARDOUS MATERIALS 424(2021).