O3-NaFe((1/3-x))Ni(1/3)Mn(1/3)AlxO(2) Cathodes with Improved Air Stability for Na-Ion Batteries

doi:10.1021/acsami.1c07554

	O3-NaFe((1/3-x))Ni(1/3)Mn(1/3)AlxO(2) Cathodes with Improved Air Stability for Na-Ion Batteries
	Li, Xiaowei 1,2; Shen, Xing 1,2; Zhao, Junmei 1,2,3; Yang, Yang 2,4; Zhang, Qiangqiang 2,4; Ding, Feixiang 1,2; Han, Miao 5; Xu, Chunliu 1; Yang, Chao 1; Liu, Huizhou 1
刊名	ACS APPLIED MATERIALS & INTERFACES
	2021-07-21
卷号	13 期号:28 页码:33015-33023
关键词	Al doping O3-NaFe((1/3-x))Ni(1/3)Mn(1/3)AlxO(2) air stability layered oxide cathodes Na-ion batteries
ISSN号	1944-8244
DOI	10.1021/acsami.1c07554
英文摘要	Na-ion batteries (NIBs) have been considered as potential candidates for large-scale energy storage, where O3-type Na-based layered oxide cathodes have attracted great attention due to their high capacity and low cost. However, O3-NaxTMO2 materials still suffer from insufficient air stability, which could lead to deteriorative electrochemical properties and thus hinder their practical application. In this work, a series of Al-doped O3-NaFe(1/3-x)Ni1/3Mn1/3AlxO2 cathodes prepared by a co-precipitation method were investigated to enhance their electrochemical performance and air stability through stabilizing their structural and interface chemical properties. The Al-doped O3- NaFe(1/3-0.01)Ni1/3Mn1/3Al0.01O2 (NFNMA(0.01)) cathode delivers a comparable capacity of 138 mAh g(-1) and keeps a capacity retention of 85.88% after 50 cycles at 0.2 C, while the undoped O3NaFe(1/3)Ni(1/3)Mn(1/3)O(2) (NFNM) can only keep a capacity retention of 71.02%, although with an initial capacity of 141 mAh g(-1) at 0.2 C. For the air stability, the capacity decay rates are 58.87 and 5.07% for the undoped NFNM and Al-doped NFNMA0.01 after the air exposure for 30 days, respectively. The greatly decaying electrochemical performance could be due to the formation of carbonates during air exposure, which can be efficiently suppressed by Al doping. The doped Al3+ has been confirmed to be inserted into the NFNM crystal lattice, inducing the reduced values of lattice parameters a and c due to the smaller ionic radius of Al3+ (53.5 pm) vs Fe3+ (55.0 pm). This study demonstrates that Al doping plays an important role in the air stability and cycling stability for layered cathode materials, which offers an efficient strategy to optimize the material design for their practical application in NIBs.
资助项目	National Natural Science Foundation of China[51872289] ; National Natural Science Foundation of China[51672275] ; Science and Technology Project of Inner Mongolia[2021GG0162] ; DNL Cooperation Fund, CAS[DNL201914] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21070500] ; National Key Technologies R&D Program, China[2016YFB0901500] ; Innovation Academy for Green Manufacture, CAS[IAGM2020C07] ; Beijing Natural Science Foundation[2182074]
WOS关键词	OXIDE ; O3-TYPE ; SUBSTITUTION ; PERFORMANCE ; STORAGE
WOS研究方向	Science & Technology - Other Topics ; Materials Science
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000677540900038
资助机构	National Natural Science Foundation of China ; Science and Technology Project of Inner Mongolia ; DNL Cooperation Fund, CAS ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Technologies R&D Program, China ; Innovation Academy for Green Manufacture, CAS ; Beijing Natural Science Foundation
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/49563]
专题	中国科学院过程工程研究所
通讯作者	Zhao, Junmei
作者单位	1.Chinese Acad Sci, CAS Key Lab Green Proc & Engn, State Key Lab Biochem Engn, Inst Proc Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Key Lab Renewable Energy, Beijing Key Lab New Energy Mat & Devices, Beijing Natl Lab Condensed Matter Phys,Inst Phys, Beijing 100190, Peoples R China 5.Beijing Inst Technol, Chongqing Innovat Ctr, Chongqing 401120, Peoples R China
推荐引用方式 GB/T 7714	Li, Xiaowei,Shen, Xing,Zhao, Junmei,et al. O3-NaFe((1/3-x))Ni(1/3)Mn(1/3)AlxO(2) Cathodes with Improved Air Stability for Na-Ion Batteries[J]. ACS APPLIED MATERIALS & INTERFACES,2021,13(28):33015-33023.
APA	Li, Xiaowei.,Shen, Xing.,Zhao, Junmei.,Yang, Yang.,Zhang, Qiangqiang.,...&Hu, Yong-Sheng.(2021).O3-NaFe((1/3-x))Ni(1/3)Mn(1/3)AlxO(2) Cathodes with Improved Air Stability for Na-Ion Batteries.ACS APPLIED MATERIALS & INTERFACES,13(28),33015-33023.
MLA	Li, Xiaowei,et al."O3-NaFe((1/3-x))Ni(1/3)Mn(1/3)AlxO(2) Cathodes with Improved Air Stability for Na-Ion Batteries".ACS APPLIED MATERIALS & INTERFACES 13.28(2021):33015-33023.