Effects of biochar nanoparticles on anticorrosive performance of zinc-rich epoxy coatings | |
Li, Ziyou1,3,4,5; Ravenni, Giulia2; Bi, Huichao1; Weinell, Claus Erik1; Ulusoy, Burak1,4,5; Zhang, Yanqiang6,7; Dam-Johansen, Kim1,2 | |
刊名 | PROGRESS IN ORGANIC COATINGS |
2021-09-01 | |
卷号 | 158页码:14 |
关键词 | Biochar nanoparticles Conductivity Corrosion EIS Zinc-rich epoxy coatings |
ISSN号 | 0300-9440 |
DOI | 10.1016/j.porgcoat.2021.106351 |
英文摘要 | Biochar nanoparticles (BCN) derived from spruce wood and wheat straw were prepared, characterized and incorporated into zinc-rich epoxy coatings, with the aim of improving the zinc powder utilization and the anticorrosion performance. Formulations with different BCN and commercial carbon black dosages (0.4 wt%, 0.8 wt% and 1.6 wt%) were compared to a zinc-rich epoxy paint (ZRP) without carbon addition. After immersion and salt spray exposure, coated steel panels were characterized with optical, electrochemical and spectroscopy techniques to evaluate the anticorrosive performance. BCN and carbon black addition enhanced the local electrochemical reactions and the barrier effects were promoted by an increased amount of zinc corrosion products (Zn5(OH)8Cl2 and ZnCO3). The formulation with 0.8 wt% of spruce wood BCN performed equivalently well compared to the ones with carbon black. The degraded area and rust accumulation around the artificial scribe for the formulation with 0.8 wt% of spruce wood BCN were 29.8% and 27.8% less than ZRP, respectively, which is attributed to the good electrical conductivity and high specific surface area of spruce wood char. These results suggest a promising and sustainable option for improving the anticorrosive performance of zinc-rich epoxy coatings by the incorporation of BCN. |
资助项目 | Hempel Foundation ; (Hempel Foundation Coatings Science and Technology Centre) |
WOS关键词 | ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY ; SCANNING ACOUSTIC MICROSCOPY ; ELECTRICAL-CONDUCTIVITY ; CORROSION PROTECTION ; ACTIVATED CARBON ; POWDER COATINGS ; WATER-UPTAKE ; GASIFICATION ; ENERGY ; BEHAVIOR |
WOS研究方向 | Chemistry ; Materials Science |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE SA |
WOS记录号 | WOS:000679109300009 |
资助机构 | Hempel Foundation ; (Hempel Foundation Coatings Science and Technology Centre) |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/49508] |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Bi, Huichao |
作者单位 | 1.Tech Univ Denmark DTU, Dept Chem & Biochem Engn, CoaST, Bldg 229, DK-2800 Lyngby, Denmark 2.Tech Univ Denmark DTU, CHEC, Dept Chem & Biochem Engn, Bldg 229, DK-2800 Lyngby, Denmark 3.Chinese Acad Sci, Inst Proc Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China 4.Univ Chinese Acad Sci, Sino Danish Coll, Beijing 100049, Peoples R China 5.Univ Chinese Acad Sci, Sino Danish Ctr Educ & Res, Beijing 100049, Peoples R China 6.Chinese Acad Sci, Key Lab Sci & Technol Particle Mat, Beijing 100190, Peoples R China 7.Inst Emerging Ind Technol, Zhengzhou 450000, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Ziyou,Ravenni, Giulia,Bi, Huichao,et al. Effects of biochar nanoparticles on anticorrosive performance of zinc-rich epoxy coatings[J]. PROGRESS IN ORGANIC COATINGS,2021,158:14. |
APA | Li, Ziyou.,Ravenni, Giulia.,Bi, Huichao.,Weinell, Claus Erik.,Ulusoy, Burak.,...&Dam-Johansen, Kim.(2021).Effects of biochar nanoparticles on anticorrosive performance of zinc-rich epoxy coatings.PROGRESS IN ORGANIC COATINGS,158,14. |
MLA | Li, Ziyou,et al."Effects of biochar nanoparticles on anticorrosive performance of zinc-rich epoxy coatings".PROGRESS IN ORGANIC COATINGS 158(2021):14. |
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