Fe-Ion-Catalyzed Synthesis of CdSe/Cu Core/Shell Nanowires

doi:10.1021/acs.inorgchem.0c03488

	Fe-Ion-Catalyzed Synthesis of CdSe/Cu Core/Shell Nanowires
	Chen, Mao 1,2; Xu, Lekai 3; Wang, Jiao 1,2; Liu, Baokun 1,2; Wang, Kun 1,2; Qi, Qi 1,2; Zhu, Yaqiong 1,2; Yang, Xin 1,2; Chai, Wencui 4; Yang, Peixu 1,2
刊名	INORGANIC CHEMISTRY
	2021-02-15
卷号	60 期号:4 页码:2614-2622
ISSN号	0020-1669
DOI	10.1021/acs.inorgchem.0c03488
英文摘要	CdSe/Cu core/shell nanowires (NWs) are successfully synthesized by a wet chemical method for the first time. By utilizing the solution-liquid-solid (SLS) mechanism, CdSe NWs are fabricated by Bi seeds, which act as catalysts. In the subsequent radial overcoating of the Cu shell on the CdSe NWs, Fe ions have been proven to be an indispensable and efficient catalyzer. The thickness of the Cu shell could be well controlled in the range of 3 to 6 nm by varying the growth temperature (from 300 to 360 degrees C). Our synthetic strategy pioneers a new possibility for the controlled synthesis of semiconductor-metal heterostructure NWs (especially for II-VI semiconductors), such as CdS/Cu, ZnS/Au, and ZnO/Ag, which had broad application prospects in photoconductors, thin-film transistors, and light-emitting diodes. Theoretically, electrons flow from a higher Fermi-level material to the bottom Fermi-level at the metal-semiconductor heterojunction interface, which aligns the Fermi level and establishes the Schottky barrier. It leads to excess negative charges in metals and excess positive charges in semiconductors. Therefore, those effective electron traps reduce the probability of photogenerated electron-hole pair recombination efficiently, which has been widely applied in solar cells, sensors, photocatalysis, and energy storage. The breakthrough and innovation of this synthesis method have opened up a new synthetic route with a mild reaction environment, low energy consumption, and convenience.
资助项目	Education Department of Henan Province[20A430024] ; National Key Research and Development Program of China[2016YFB0301001]
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000620345400052
资助机构	Education Department of Henan Province ; National Key Research and Development Program of China
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/47944]
专题	中国科学院过程工程研究所
通讯作者	Du, Jiang
作者单位	1.Zhengzhou Univ, Henan Prov Ind Technol Res Inst Resources & Mat, Zhengzhou 450001, Peoples R China 2.Zhengzhou Univ, Sch Mat Sci & Engn, Zhengzhou 450001, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, State Key Lab Biochem Engn, Beijing 100109, Peoples R China 4.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Peoples R China 5.Henan Univ, Sch Phys & Elect, Kaifeng 475004, Peoples R China
推荐引用方式 GB/T 7714	Chen, Mao,Xu, Lekai,Wang, Jiao,et al. Fe-Ion-Catalyzed Synthesis of CdSe/Cu Core/Shell Nanowires[J]. INORGANIC CHEMISTRY,2021,60(4):2614-2622.
APA	Chen, Mao.,Xu, Lekai.,Wang, Jiao.,Liu, Baokun.,Wang, Kun.,...&Du, Jiang.(2021).Fe-Ion-Catalyzed Synthesis of CdSe/Cu Core/Shell Nanowires.INORGANIC CHEMISTRY,60(4),2614-2622.
MLA	Chen, Mao,et al."Fe-Ion-Catalyzed Synthesis of CdSe/Cu Core/Shell Nanowires".INORGANIC CHEMISTRY 60.4(2021):2614-2622.