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Enhanced negative thermal expansion of boron-doped Fe43Mn28Ga28.97B0.03 alloy
Sun, X. M.1,4; Cong, D. Y.4; Ren, Y.3; Brown, D. E.2,3; Gallington, L. C.3; Li, R. G.4; Cao, Y. X.4; Chen, Z.4; Li, S. H.4; Nie, Z. H.5
刊名JOURNAL OF ALLOYS AND COMPOUNDS
2021-03-15
卷号857页码:7
关键词Negative thermal expansion Martensitic transformation Chemical substitution Magnetic functional materials
ISSN号0925-8388
DOI10.1016/j.jallcom.2020.157572
英文摘要Enhanced negative thermal expansion (NTE) properties are achieved by introducing a little amount of boron in the Fe43Mn28Ga28.97B0.03 alloy. As a result, this alloy shows a giant NTE coefficient of alpha(1) = -79.7 x 10(-6) K-1 in a wide temperature range from 277 K to 136 K. Compared to the NTE characteristics in Fe43Mn28Ga29, the NTE operation temperature window has expanded by 74% with the corresponding coefficient of thermal expansion increased by 57% within the NTE temperature window for the boron-doped Fe43Mn28Ga28.97B0.03. In-situ synchrotron high-energy X-ray diffraction results suggest that by boron substitution, the large unit cell volume change across martensitic transformation and the wide phase transition temperature interval are responsible for the pronounced NTE behavior in Fe43Mn28Ga28.97B0.03. Moreover, for the Fe43Mn28Ga28.97B0.03 NTE material, the compressive strength and strain are significantly improved compared with that of Fe43Mn28Ga29. The present study indicates that Fe43Mn28Ga28.97B0.03 with enhanced NTE across martensitic transformation may be used for practical application as thermal-expansion compensators. (C) 2020 Elsevier B.V. All rights reserved.
资助项目National Natural Science Foundation of China[51731005] ; National Natural Science Foundation of China[51822102] ; National Natural Science Foundation of China[51671180] ; Fundamental Research Funds for the Central Universities[FRF-TP-18-008C1] ; U.S. Department of Energy, Office of Science, Office of Basic Energy Science[DE-AC02-06CH11357]
WOS关键词MECHANICAL-PROPERTIES ; MAGNETIC-PROPERTIES ; TRANSITION ; MAGNETOSTRICTION ; MICROSTRUCTURE ; TRANSFORMATION
WOS研究方向Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
出版者ELSEVIER SCIENCE SA
WOS记录号WOS:000610867800050
资助机构National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; U.S. Department of Energy, Office of Science, Office of Basic Energy Science
内容类型期刊论文
源URL[http://ir.ipe.ac.cn/handle/122111/43384]  
专题中国科学院过程工程研究所
通讯作者Cong, D. Y.
作者单位1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
2.Northern Illinois Univ, Dept Phys, De Kalb, IL 60115 USA
3.Argonne Natl Lab, Xray Sci Div, Argonne, IL 60439 USA
4.Univ Sci & Technol Beijing, Beijing Adv Innovat Ctr Mat Genome Engn, State Key Lab Adv Met & Mat, Beijing 100083, Peoples R China
5.Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
6.Qufu Normal Univ, Expt Teaching & Equipment Management Ctr, Qufu 273165, Shandong, Peoples R China
推荐引用方式
GB/T 7714
Sun, X. M.,Cong, D. Y.,Ren, Y.,et al. Enhanced negative thermal expansion of boron-doped Fe43Mn28Ga28.97B0.03 alloy[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2021,857:7.
APA Sun, X. M..,Cong, D. Y..,Ren, Y..,Brown, D. E..,Gallington, L. C..,...&Wang, Y. D..(2021).Enhanced negative thermal expansion of boron-doped Fe43Mn28Ga28.97B0.03 alloy.JOURNAL OF ALLOYS AND COMPOUNDS,857,7.
MLA Sun, X. M.,et al."Enhanced negative thermal expansion of boron-doped Fe43Mn28Ga28.97B0.03 alloy".JOURNAL OF ALLOYS AND COMPOUNDS 857(2021):7.
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