Environmentally benign process for selective recovery of valuable metals from spent lithium-ion batteries by using conventional sulfation roasting

doi:10.1039/c9gc01350d

	Environmentally benign process for selective recovery of valuable metals from spent lithium-ion batteries by using conventional sulfation roasting
	Lin, Jiao 1,2; Liu, Chunwei 1; Cao, Hongbin 1; Chen, Renjie 2; Yang, Yongxia 1; Li, Li 2; Sun, Zhi 1,2
刊名	GREEN CHEMISTRY
	2019-11-07
卷号	21 期号:21 页码:5904-5913
ISSN号	1463-9262
DOI	10.1039/c9gc01350d
英文摘要	Recycling of spent lithium-ion batteries (LIBs) has attracted intensive attention owing to their potential environmental risk and the importance of the supply of critical metals. Sulfation roasting as a traditional technology is not considered environmentally friendly due to serious SOx emission. The usage of over-stoichiometric amounts of sodium salt results in high sodium content in the leaching solutions bringing about difficulties for the preparation of qualified lithium products. It is usually not easy to achieve high recovery selectivity of metals. Herein, we find it is possible to eliminate secondary emission and no sodium is included in the process of spent LIB (LiCoO2 as a case study) recycling if the transfer pathway of sulfur among different phases is well controlled. At the same time, high lithium recovery selectivity is achieved. The principles of green chemistry for substitution of chemicals with a low environmental impact and improving the atomic efficiency of sulfur are introduced during traditional sulfation roasting. A pretreatment step of aging with sulfuric acid at 393 K is introduced to form cobalt sulfate which in the following heat treatment step will further preferentially react with the remaining LiCoO2 until it is completely consumed. By controlling the amount of sulfuric acid, sulfur can be recirculated and recycled thoroughly in the form of SO42-, instead of SOx emission and the atomic efficiency of sulfur can be highly improved. After leaching with water, the concentration of Li+ in the leachate reaches 19.82 g L-1; 99.3% lithium and 98.7% cobalt were recuperated as Li2CO3 and Co3O4 with a purity of 99.89% and 99.95%, respectively. Our findings propose an environmentally benign and easily implemented strategy for selective recycling of spent LIBs. The fundamentals provide inspiration for separation and extraction fields such as mining and recycling of complex systems composed of multiple metals.
资助项目	National Key Research and Development Program of China[2017YFB0403300/2017YFB0403305] ; National Natural Science Foundation of China[51425405] ; National Natural Science Foundation of China[51874269] ; Key Program of Chinese Academy of Sciences[KFZD-SW-315] ; China Postdoctoral Science Foundation[2018M631579] ; 1000 Talents Program of China
WOS关键词	CATHODE MATERIALS ; LICOO2 ; SEPARATION ; COBALT ; LI ; ACID ; CARBONATE ; MANGANESE ; REAGENTS ; DIVALENT
WOS研究方向	Chemistry ; Science & Technology - Other Topics
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000493077100012
资助机构	National Key Research and Development Program of China ; National Natural Science Foundation of China ; Key Program of Chinese Academy of Sciences ; China Postdoctoral Science Foundation ; 1000 Talents Program of China
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/38990]
专题	中国科学院过程工程研究所
通讯作者	Li, Li; Sun, Zhi
作者单位	1.Chinese Acad Sci, Beijing Engn Res Ctr Proc Pollut Control, Div Environm Technol & Engn, Inst Proc Engn, Beijing 100190, Peoples R China 2.Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
推荐引用方式 GB/T 7714	Lin, Jiao,Liu, Chunwei,Cao, Hongbin,et al. Environmentally benign process for selective recovery of valuable metals from spent lithium-ion batteries by using conventional sulfation roasting[J]. GREEN CHEMISTRY,2019,21(21):5904-5913.
APA	Lin, Jiao.,Liu, Chunwei.,Cao, Hongbin.,Chen, Renjie.,Yang, Yongxia.,...&Sun, Zhi.(2019).Environmentally benign process for selective recovery of valuable metals from spent lithium-ion batteries by using conventional sulfation roasting.GREEN CHEMISTRY,21(21),5904-5913.
MLA	Lin, Jiao,et al."Environmentally benign process for selective recovery of valuable metals from spent lithium-ion batteries by using conventional sulfation roasting".GREEN CHEMISTRY 21.21(2019):5904-5913.