Facile and green synthesis of highly dispersed tar-based heterogeneous Fenton catalytic nanoparticles for the degradation of methylene blue

doi:10.1016/j.jclepro.2019.119033

	Facile and green synthesis of highly dispersed tar-based heterogeneous Fenton catalytic nanoparticles for the degradation of methylene blue
	Li, Dong 3,4; Yang, Tianxue 2; Li, Yi 1; Liu, Zhengang 3,4; Jiao, Wentao 3,4
刊名	JOURNAL OF CLEANER PRODUCTION
	2020-02-10
卷号	246 页码:11
关键词	Nanoparticles Biomass tar Fenton catalyst Hydrogen peroxide Metallic oxide
ISSN号	0959-6526
DOI	10.1016/j.jclepro.2019.119033
英文摘要	Thermochemical conversion of biomass produces tar, as an inevitable byproduct, which was a potentially precursor for carbon material preparation. This study provided an approach of preparation of tar-based Fenton-like catalytic nanoparticles from waste biomass tar via green solvent-free approach. The monoand bimetallic nanocatalysts were synthesized from biomass tar and metal salts by ball milling combined with calcination. The synthesized catalysts were utilized for H2O2 decomposition and subsequent methylene blue (MB) degradation in aqueous solution. The results showed that the presence of tar resulted in the porous structure and defective graphite layers on the surface of resultant catalysts. The bimetallic nanocatalysts had higher H2O2 decomposition rate than monometallic nanocatalysts and among all the catalysts, the bimetal catalyst prepared at 300 degrees C (FeNi/C-300) showed the highest rate constant (10.55 x 10(-3) min(-1)) for the decomposition of H2O2. This high catalytic activity of FeNi/C-300 was attributed to the promotion of Fe3+ reducing to Fe2+ due to accelerated electron exchange by the introduction of nickel and the formation of defective graphite layers. For MB degradation, the monometal nanocatalyst prepared at 300 degrees C (Fe/C-300) and FeNi/C-300 showed high removal efficient in the degradation of methylene blue, and the highest removal efficiency reached 100% and 98%, respectively. This study offered a promising approach for the preparation of heterogeneous Fenton catalytic nanoparticles for organic pollutant removal using waste biomass tar and by green synthesis method. Most importantly, this approach has the potential to be extended for other metal based Fenton catalytic nanoparticles synthesis. (C) 2019 Elsevier Ltd. All rights reserved.
资助项目	"100 Talents" Program of the Chinese Academy of Sciences[Y5N41I1C01]
WOS关键词	HYDROGEN-PEROXIDE ; POROUS CARBONS ; SURFACE-AREA ; IRON ; OXIDATION ; COMPOSITE ; OXIDES ; ACID ; DECOMPOSITION ; REDUCTION
WOS研究方向	Science & Technology - Other Topics ; Engineering ; Environmental Sciences & Ecology
语种	英语
出版者	ELSEVIER SCI LTD
WOS记录号	WOS:000504632600088
资助机构	"100 Talents" Program of the Chinese Academy of Sciences
内容类型	期刊论文
源URL	[http://ir.ipe.ac.cn/handle/122111/38593]
专题	中国科学院过程工程研究所
通讯作者	Liu, Zhengang; Jiao, Wentao
作者单位	1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Chinese Res Inst Environm Sci, State Key Lab Environm Criteria & Risk Assessment, Beijing 100012, Peoples R China 3.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, 18 Shuangqing Rd, Beijing 100085, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Li, Dong,Yang, Tianxue,Li, Yi,et al. Facile and green synthesis of highly dispersed tar-based heterogeneous Fenton catalytic nanoparticles for the degradation of methylene blue[J]. JOURNAL OF CLEANER PRODUCTION,2020,246:11.
APA	Li, Dong,Yang, Tianxue,Li, Yi,Liu, Zhengang,&Jiao, Wentao.(2020).Facile and green synthesis of highly dispersed tar-based heterogeneous Fenton catalytic nanoparticles for the degradation of methylene blue.JOURNAL OF CLEANER PRODUCTION,246,11.
MLA	Li, Dong,et al."Facile and green synthesis of highly dispersed tar-based heterogeneous Fenton catalytic nanoparticles for the degradation of methylene blue".JOURNAL OF CLEANER PRODUCTION 246(2020):11.