Scalable Synthesis Nano-Perovskite K(Mn0.95Ni0.05)F-3 Cathode by Homogeneous Precipitation Method for Potassium-Ion Batteries | |
Wang, Shuya; Cui, Bin; Zhuang, Quanchao; Shi, Yueli; Zheng, Hong | |
刊名 | NANOSCALE RESEARCH LETTERS |
2019-07-16 | |
卷号 | 14 |
ISSN号 | 1931-7573 |
DOI | 10.1186/s11671-019-3056-1 |
英文摘要 | Potassium-ion batteries (KIBs) are favored by researchers because of the unique advantages. In this work, KIB cathode material nano-perovskite K(Mn0.95Ni0.05)F-3 with concentration gradient was synthesized by EDTA-assisted homogeneous precipitation method for the first time and characterized. The solid solution material was deposited on the multi-walled carbon nanotubes (MWCNTs) to form K(Mn0.95Ni0.05)F-3/MWCNT nanocomposites to improve the electron conductivity of the electrode material so as to obtain the excellent electrochemical performance. As expected, the charge and discharge capacities of K(Mn0.95Ni0.05)F-3/MWCNTs after the 60th cycle can still reach 106.8 and 98.5 mAh g(-1) over the voltage range 4.2-1.2V vs. K/K+ at the current density of 35mAg(-1), respectively. Electrochemical performance studies showed that solid solution K(Mn0.95Ni0.05)F-3 had the potential applications as the cathode material for KIBs. Electrochemical impedance spectroscopy (EIS) was used to study the transport and reaction processes of ions at the solid-liquid interface. The main factors affecting electrochemical performance could be analyzed from the Nyquist plot of the EIS test. |
内容类型 | 期刊论文 |
源URL | [http://ir.isl.ac.cn/handle/363002/34103] |
专题 | 青海盐湖研究所_盐湖资源与化学实验室 青海盐湖研究所_盐湖资源综合利用工程技术中心 中国科学院青海盐湖研究所 |
推荐引用方式 GB/T 7714 | Wang, Shuya,Cui, Bin,Zhuang, Quanchao,et al. Scalable Synthesis Nano-Perovskite K(Mn0.95Ni0.05)F-3 Cathode by Homogeneous Precipitation Method for Potassium-Ion Batteries[J]. NANOSCALE RESEARCH LETTERS,2019,14. |
APA | Wang, Shuya,Cui, Bin,Zhuang, Quanchao,Shi, Yueli,&Zheng, Hong.(2019).Scalable Synthesis Nano-Perovskite K(Mn0.95Ni0.05)F-3 Cathode by Homogeneous Precipitation Method for Potassium-Ion Batteries.NANOSCALE RESEARCH LETTERS,14. |
MLA | Wang, Shuya,et al."Scalable Synthesis Nano-Perovskite K(Mn0.95Ni0.05)F-3 Cathode by Homogeneous Precipitation Method for Potassium-Ion Batteries".NANOSCALE RESEARCH LETTERS 14(2019). |
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