Synthesis, Crystal Structure, and Thermal Property of a Potassium-ammonium Double Salt K-0.48(NH4)(0.52)MgCl3 center dot 6H(2)O

doi:10.1134/S1063774519020135

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	Synthesis, Crystal Structure, and Thermal Property of a Potassium-ammonium Double Salt K-0.48(NH4)(0.52)MgCl3 center dot 6H(2)O
	Yang, Hongjun; Chen, Yanmei; Wang, Min; Li, Bing
刊名	CRYSTALLOGRAPHY REPORTS
	2019-03
卷号	64 期号:2 页码:277-281
ISSN号	1063-7745
DOI	10.1134/S1063774519020135
英文摘要	By evaporating the brine containing potassium and ammonium cations compound of the composition K-0.48(NH4)(0.52)MgCl3 6H(2)O was obtained. Its crystal structure was determined by single crystal X-ray analysis. In the crystal, monovalent cation consists of 52% of ammonium and 48% of potassium. The crystal structure consists of a network of (N,K)Cl-6 octahedra and Mg(H2O)(6) octahedra occupying the cavities in this network. Its unit cell parameters are similar to those of ammonium carnallite. There are obvious differences between the crystal structure of carnallite and the compound. IR spectra show that both carnallite and ammonium chloride characteristic peaks are detected. The thermal behaviour was also investigated.
内容类型	期刊论文
源URL	[http://ir.isl.ac.cn/handle/363002/34090]
专题	青海盐湖研究所_盐湖资源与化学实验室中国科学院青海盐湖研究所
推荐引用方式 GB/T 7714	Yang, Hongjun,Chen, Yanmei,Wang, Min,et al. Synthesis, Crystal Structure, and Thermal Property of a Potassium-ammonium Double Salt K-0.48(NH4)(0.52)MgCl3 center dot 6H(2)O[J]. CRYSTALLOGRAPHY REPORTS,2019,64(2):277-281.
APA	Yang, Hongjun,Chen, Yanmei,Wang, Min,&Li, Bing.(2019).Synthesis, Crystal Structure, and Thermal Property of a Potassium-ammonium Double Salt K-0.48(NH4)(0.52)MgCl3 center dot 6H(2)O.CRYSTALLOGRAPHY REPORTS,64(2),277-281.
MLA	Yang, Hongjun,et al."Synthesis, Crystal Structure, and Thermal Property of a Potassium-ammonium Double Salt K-0.48(NH4)(0.52)MgCl3 center dot 6H(2)O".CRYSTALLOGRAPHY REPORTS 64.2(2019):277-281.