Asymmetric addition of benzothiazole to N-tert-butanesulfinyl imine for the synthesis of chiral a-branched heteroaryl amines

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	Asymmetric addition of benzothiazole to N-tert-butanesulfinyl imine for the synthesis of chiral a-branched heteroaryl amines
	Zhang JL(张金龙) ; Yang YH(杨玉红) ; Wang M(王梅) ; Lin L(林利) ; Wang R(王锐)
刊名	Tetrahedron Letters
	2012
卷号	53 页码:6893-6896
关键词	Asymmetric synthesis Benzothiazole Diarylmethylamine Diastereoselectivity N-tert-Butanesulfinyl imine
ISSN号	0040-4039
通讯作者	林利 ; 王锐
中文摘要	This work concerns the asymmetric additions of benzothiazole to a variety of N-tert-butanesulfinyl imines with excellent diastereoselectivities (d.r. up to >99:1). Amino alkoxyl lithium was the key additive to obtain the excellent diastereoselectivity. More functionalized 4-methyl-5-vinyl thiazole and alkyl imines which can isomerize to enamines are also compatible substrates to the present protocol.
学科主题	物理化学
收录类别	SCI
资助信息	NSFC (nos. 21002043;21272107;20932003);the National S&T Major Project of China (2012ZX09504-001-003);Fundamental Research Funds for the Central Universities (lzujbky-2010-184)
语种	英语
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/3882]
专题	兰州化学物理研究所_OSSO国家重点实验室
推荐引用方式 GB/T 7714	Zhang JL,Yang YH,Wang M,et al. Asymmetric addition of benzothiazole to N-tert-butanesulfinyl imine for the synthesis of chiral a-branched heteroaryl amines[J]. Tetrahedron Letters,2012,53:6893-6896.
APA	张金龙,杨玉红,王梅,林利,&王锐.(2012).Asymmetric addition of benzothiazole to N-tert-butanesulfinyl imine for the synthesis of chiral a-branched heteroaryl amines.Tetrahedron Letters,53,6893-6896.
MLA	张金龙,et al."Asymmetric addition of benzothiazole to N-tert-butanesulfinyl imine for the synthesis of chiral a-branched heteroaryl amines".Tetrahedron Letters 53(2012):6893-6896.