A Lewis acid-promoted reduction of acylsilanes to alpha-hydroxysilanes by diethylzinc

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	A Lewis acid-promoted reduction of acylsilanes to alpha-hydroxysilanes by diethylzinc
	Gao G(高广)1; Bai XF(柏惺峰)1; Li F(李菲)1; Zheng LS(郑龙生)1; Zheng ZJ(郑战江)1; Lai GQ(来国桥)1; Jiang KZ(蒋可志)1; Li FW(李福伟)2 ; Xu LW(徐利文)1
刊名	Tetrahedron Letters
	2012
卷号	53 期号:17 页码:2164-2166
关键词	Organosilicon chemistry Reduction Diethylzinc Silane Lewis acid
ISSN号	0040-4039
通讯作者	徐利文
英文摘要	We report here the first example of the reduction of acylsilanes to α-hydroxysilanes, in which diethylzinc was used as a highly reactive agent in the presence of Ti(OiPr)₄ or other Lewis acids. The reduction typically proceeds to give synthetically useful α-hydroxysilanes in good yields.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Natural Science Founder of China (No. 20973051;21173064);Program for Excellent Young Teachers in Hangzhou Normal University (HNUEYT);Zhejiang Provincial Natural Science Foundation of China (Y4090139)
语种	英语
WOS记录号	WOS:000302587800005
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/3881]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Gao G,Bai XF,Li F,et al. A Lewis acid-promoted reduction of acylsilanes to alpha-hydroxysilanes by diethylzinc[J]. Tetrahedron Letters,2012,53(17):2164-2166.
APA	Gao G.,Bai XF.,Li F.,Zheng LS.,Zheng ZJ.,...&Xu LW.(2012).A Lewis acid-promoted reduction of acylsilanes to alpha-hydroxysilanes by diethylzinc.Tetrahedron Letters,53(17),2164-2166.
MLA	Gao G,et al."A Lewis acid-promoted reduction of acylsilanes to alpha-hydroxysilanes by diethylzinc".Tetrahedron Letters 53.17(2012):2164-2166.