Mn-II complexes with tetradentate N-4 ligands: Highly efficient catalysts for the epoxidation of olefins with H2O2

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	Mn-II complexes with tetradentate N-4 ligands: Highly efficient catalysts for the epoxidation of olefins with H2O2
	Yu SJ(于松杰)1,2; Miao CX(苗成霞)1 ; Wang DQ(王大奇)3; Wang SF(王寿峰)1 ; Xia CG(夏春谷)1 ; Sun W(孙伟)1
刊名	Journal of Molecular Catalysis A: Chemical
	2012
卷号	353 页码:185-191
关键词	N ligands Manganese Epoxidation Hydrogen peroxide Olefins
ISSN号	1381-1169
通讯作者	孙伟
英文摘要	A series of Mn-complexes with tetradentate N₄ ligands, introducing aromatic groups into 2-pyridylmethyl positions of N,N′-dimethyl-N,N′-bis(2-pyridylmethyl)ethane-1,2-diamine (mep), N,N′-dimethyl-N,N′-bis(2-pyridylmethyl)cyclohexane-trans-diamine (mcp), have been synthesized and applied for epoxidation of olefins using H₂O₂ as the oxidant. The Mn-complexes still possessed an octahedral mononuclear structure in a cis-α topology. These complexes showed good regioselectivity, high yields and turnover frequency (even up to 228,000 h⁻¹) with low catalyst loading (0.1–0.01 mol%) for epoxidation of a family of olefins (including internal aromatic olefins, internal and terminal aliphatic olefins and diolefins).
学科主题	物理化学
收录类别	SCI
资助信息	the Chinese Academy of Sciences;the National Natural Science Foundation of China (20873166;21073210;21133011)
语种	英语
WOS记录号	WOS:000300032700026
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/3872]
专题	兰州化学物理研究所_OSSO国家重点实验室
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Peoples R China
推荐引用方式 GB/T 7714	Yu SJ,Miao CX,Wang DQ,et al. Mn-II complexes with tetradentate N-4 ligands: Highly efficient catalysts for the epoxidation of olefins with H2O2[J]. Journal of Molecular Catalysis A: Chemical,2012,353:185-191.
APA	Yu SJ,Miao CX,Wang DQ,Wang SF,Xia CG,&Sun W.(2012).Mn-II complexes with tetradentate N-4 ligands: Highly efficient catalysts for the epoxidation of olefins with H2O2.Journal of Molecular Catalysis A: Chemical,353,185-191.
MLA	Yu SJ,et al."Mn-II complexes with tetradentate N-4 ligands: Highly efficient catalysts for the epoxidation of olefins with H2O2".Journal of Molecular Catalysis A: Chemical 353(2012):185-191.