Oxygen-sulfur rearrangement in the reaction of thiocarbamate imidazolium ylide with arylaldehyde

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	Oxygen-sulfur rearrangement in the reaction of thiocarbamate imidazolium ylide with arylaldehyde
	Zhao YW(赵应伟); Lei M(雷敏); Yang L(杨磊); Han F(韩峰); Li Z(李臻); Xia CG(夏春谷); Xia CG(夏春谷)
刊名	Organic and Biomolecular Chemistry
	2012
卷号	10 期号:45 页码:8956-8959
ISSN号	1477-0520
通讯作者	夏春谷
英文摘要	The nucleophilic addition of thiocarbamate imidazolium ylide to aldehyde triggered sequential intramolecular N to O migration of thiocarbonyl amide group and reversible oxygen–sulfur rearrangement to afford 2-imidazolium alkylcarbamothioate. The ortho group on phenyl of aldehyde strongly affects the balance of the O- to S-rearrangement.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the National Natural Science Foundation of China (NSFC) (grant numbers 21133011;21173241)
语种	英语
WOS记录号	WOS:000310809100005
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/3854]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Xia CG(夏春谷)
作者单位	Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Zhao YW,Lei M,Yang L,et al. Oxygen-sulfur rearrangement in the reaction of thiocarbamate imidazolium ylide with arylaldehyde[J]. Organic and Biomolecular Chemistry,2012,10(45):8956-8959.
APA	Zhao YW.,Lei M.,Yang L.,Han F.,Li Z.,...&夏春谷.(2012).Oxygen-sulfur rearrangement in the reaction of thiocarbamate imidazolium ylide with arylaldehyde.Organic and Biomolecular Chemistry,10(45),8956-8959.
MLA	Zhao YW,et al."Oxygen-sulfur rearrangement in the reaction of thiocarbamate imidazolium ylide with arylaldehyde".Organic and Biomolecular Chemistry 10.45(2012):8956-8959.