Novel Fe-Based Amorphous Composite Coating with a Unique Interfacial Layer Improving Thermal Barrier Application

doi:10.1021/acsami.0c22868

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	Novel Fe-Based Amorphous Composite Coating with a Unique Interfacial Layer Improving Thermal Barrier Application
	Zhou, Zheng 2; Han, Feng-Xi 2; Yao, Hai-Hua 3; Li, Yan-Ze 2; Yang, Yan-Ge 1; Guo, Xing-Ye 2; Tan, Zhen 2; Xue, Yun-Fei 3; He, Ding-Yong 2; Wang, Lu 3
刊名	ACS APPLIED MATERIALS & INTERFACES
	2021-05-19
卷号	13 期号:19 页码:23057-23066
关键词	Fe-based amorphous alloy composite coating interfacial layer thermal conductivity fracture toughness
ISSN号	1944-8244
DOI	10.1021/acsami.0c22868
通讯作者	Yao, Hai-Hua(yaohaihua@bit.edu.cn)
英文摘要	To improve thermal barrier applications in advanced vehicle engines, a novel Fe-based amorphous composite coating was designed by introducing ceramic oxides and was prepared by atmospheric plasma spraying (APS). The microstructure and related properties of the as-deposited coating were investigated in detail. The composite coating comprises a well-formed FeCrNbBSi amorphous metallic matrix and dispersed yttria-stabilized zirconia (YSZ) splats. A unique Si-oxide interfacial layer with a thickness of several nanometers and an amorphous structure forms between the metallic matrix and ceramic phase, which is attributed to a combination of multiple effects. The composite coating displays extremely low thermal conductivity from 2.28 W/mK at 100 degrees C to 3.36 W/mK at 600 degrees C and can increase the surface temperature of the piston crown by 18.93 degrees C, which implies a significant means of enhancing the power efficiency. The improved thermal barrier ability of the composite coating is revealed as the crucial effect of the Si-oxide interfacial layer, which induces an increased interfacial thermal resistance. The fracture toughness of the composite coating remains at 3.40 MPa.m(1/2), comparable to that of the monolithic amorphous coating, 3.74 MPa.m(1/2), which is closely related to the formation of a Si-oxide layer and its nanoscale thickness. Therefore, the Fe-based amorphous composite coating developed here demonstrates great potential as an innovative metal-based thermal barrier coating for application in vehicle engines and provides specific inspiration for future works exploring the interfacial engineering of coating.
资助项目	National Natural Science Foundation of China[51771005] ; National Natural Science Foundation of China[52001025] ; China Postdoctoral Science Foundation[2018M641211] ; Beijing Natural Science Foundation[2194067] ; National Key R&D Program of China[2017YFB0306100]
WOS研究方向	Science & Technology - Other Topics ; Materials Science
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000655027500095
资助机构	National Natural Science Foundation of China ; China Postdoctoral Science Foundation ; Beijing Natural Science Foundation ; National Key R&D Program of China
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/160379]
专题	金属研究所_中国科学院金属研究所
通讯作者	Yao, Hai-Hua
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China 2.Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China 3.Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
推荐引用方式 GB/T 7714	Zhou, Zheng,Han, Feng-Xi,Yao, Hai-Hua,et al. Novel Fe-Based Amorphous Composite Coating with a Unique Interfacial Layer Improving Thermal Barrier Application[J]. ACS APPLIED MATERIALS & INTERFACES,2021,13(19):23057-23066.
APA	Zhou, Zheng.,Han, Feng-Xi.,Yao, Hai-Hua.,Li, Yan-Ze.,Yang, Yan-Ge.,...&Wang, Lu.(2021).Novel Fe-Based Amorphous Composite Coating with a Unique Interfacial Layer Improving Thermal Barrier Application.ACS APPLIED MATERIALS & INTERFACES,13(19),23057-23066.
MLA	Zhou, Zheng,et al."Novel Fe-Based Amorphous Composite Coating with a Unique Interfacial Layer Improving Thermal Barrier Application".ACS APPLIED MATERIALS & INTERFACES 13.19(2021):23057-23066.