Polyelectrolytes of Inorganic Polyoxometalates: Acids, Salts, and Complexes

doi:10.1021/acs.macromol.1c00783

CORC > 金属研究所 > 中国科学院金属研究所

	Polyelectrolytes of Inorganic Polyoxometalates: Acids, Salts, and Complexes
	Lu, Zhuo-Qun 1; Zhang, Lan-Lan 1; Yan, Yukun 2; Wang, Wei 1
刊名	MACROMOLECULES
	2021-07-27
卷号	54 期号:14 页码:6891-6900
ISSN号	0024-9297
DOI	10.1021/acs.macromol.1c00783
通讯作者	Wang, Wei(weiwang@nankai.edu.cn)
英文摘要	Hybrid polyelectrolytes comprising a polynorbornene backbone and pendant polyoxometalate (POM) groups, with different degrees of polymerization (DP = 100, 200, and 400), are described. The tetrabutylammonium counterions associated with the POM [(P2V3W15O62)(9-); molecular weight = 3964 Da] groups were exchanged for protons and alkali-metal cations by two cation-exchange methods, without breaking the covalent bond between the POM cluster and the polymer chain. The structural integrity of the POM clusters, which is maintained in anionic polyelectrolytes with ionization numbers ranging from 1.1-4.8 to above six, enables their combination with chiral organic cations to induce chiroptical activity in POMs and with polycations to form polyelectrolyte complexes. We compared the ionization behavior of POM polyelectrolytes with those of POM hybrids and inorganic POM clusters. POM polyelectrolytes have promising applications in electrochemistry, catalysis, and materials science, as well as in electrochromic and photochromic devices.
资助项目	National Natural Science Foundation of China[NSFC 92061120]
WOS研究方向	Polymer Science
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000679398200027
资助机构	National Natural Science Foundation of China
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/159681]
专题	金属研究所_中国科学院金属研究所
通讯作者	Wang, Wei
作者单位	1.Nankai Univ, Inst Polymer Chem, Ctr Synthet Soft Mat, Minist Educ,Key Lab Funct Polymer Mat, Tianjin 300071, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Lu, Zhuo-Qun,Zhang, Lan-Lan,Yan, Yukun,et al. Polyelectrolytes of Inorganic Polyoxometalates: Acids, Salts, and Complexes[J]. MACROMOLECULES,2021,54(14):6891-6900.
APA	Lu, Zhuo-Qun,Zhang, Lan-Lan,Yan, Yukun,&Wang, Wei.(2021).Polyelectrolytes of Inorganic Polyoxometalates: Acids, Salts, and Complexes.MACROMOLECULES,54(14),6891-6900.
MLA	Lu, Zhuo-Qun,et al."Polyelectrolytes of Inorganic Polyoxometalates: Acids, Salts, and Complexes".MACROMOLECULES 54.14(2021):6891-6900.