Nanoscale Pd Supported on Layered Co(OH)(2) as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol

doi:10.1002/slct.202101673

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	Nanoscale Pd Supported on Layered Co(OH)(2) as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol
	Lv, Lin 1; Wang, Yongzhao 2; Peng, Dengchao 1; Zhou, Zhiyuan 1; Shang, Jing 1; Guo, Wenyao 1; Zhang, Bingsen 2; Xin, Zhiling 1
刊名	CHEMISTRYSELECT
	2021-08-06
卷号	6 期号:29 页码:7384-7390
关键词	Benzyl alcohol Layered Co(OH)(2) Oxidation Pd nanoparticles Supported catalysts
ISSN号	2365-6549
DOI	10.1002/slct.202101673
通讯作者	Guo, Wenyao(guowenyao@shiep.edu.cn) ; Zhang, Bingsen(bszhang@imr.ac.cn) ; Xin, Zhiling(xinzhiling@126.com)
英文摘要	In this work, two-dimensional (2D) Co(OH)(2) nanosheets, with large surface areas and wrinkles are obtained, and used to support Pd nanoparticles (NPs) by simple impregnation method as an efficient catalyst for the oxidation of benzyl alcohol under solvent-free conditions. The resulting 1 wt.% Pd/Co(OH)(2) catalyst exhibits a high turnover frequency value of 57999 h(-1). The catalysts were characterized by SEM, TEM, AFM, XRD, BET, XPS and CO-pulse chemisorption. The results of characterizations reveal that the Pd NPs are highly dispersed on the Co(OH)(2) nanosheets. The abundant hydroxyl groups on the surface of Co(OH)(2) nanosheets promote the reduction of Pd species, resulting in a higher proportion of Pd-0 than that of Pd/AC catalyst, which further facilitates the catalytic performances.
资助项目	National Natural Science Foundation of China[21773269] ; Liao Ning Revitalization Talents Program[XLYC1807175]
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000680162200016
资助机构	National Natural Science Foundation of China ; Liao Ning Revitalization Talents Program
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/159312]
专题	金属研究所_中国科学院金属研究所
通讯作者	Guo, Wenyao; Zhang, Bingsen; Xin, Zhiling
作者单位	1.Shanghai Univ Elect Power, Shanghai Key Lab Mat Protect & Adv Mat Elect Powe, Shanghai 200090, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
推荐引用方式 GB/T 7714	Lv, Lin,Wang, Yongzhao,Peng, Dengchao,et al. Nanoscale Pd Supported on Layered Co(OH)(2) as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol[J]. CHEMISTRYSELECT,2021,6(29):7384-7390.
APA	Lv, Lin.,Wang, Yongzhao.,Peng, Dengchao.,Zhou, Zhiyuan.,Shang, Jing.,...&Xin, Zhiling.(2021).Nanoscale Pd Supported on Layered Co(OH)(2) as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol.CHEMISTRYSELECT,6(29),7384-7390.
MLA	Lv, Lin,et al."Nanoscale Pd Supported on Layered Co(OH)(2) as Efficient Catalysts for Solvent-Free Oxidation of Benzyl Alcohol".CHEMISTRYSELECT 6.29(2021):7384-7390.