Synthesis of micro/meso porous carbon for ultrahigh hydrogen adsorption using cross-linked polyaspartic acid | |
Wei, Jun; Zhao, Jianbo; Cai, Di; Ren, Wenqiang; Cao, Hui; Tan, Tianwei | |
刊名 | FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING |
2020-10 | |
卷号 | 14期号:5页码:857-867 |
关键词 | porous carbon multilevel pores polyaspartic acid cross-linking hydrogen adsorption |
ISSN号 | 2095-0179 |
英文摘要 | In addition to the specific surface area, surface topography and characteristics such as the pore size, pore size distribution, and micro/mesopores ratio are factors that determine the performance of porous carbons (PCs) in the fields of energy, catalysis, and adsorption. Based on the mechanism of weight loss of polyaspartic acid at high temperatures, this study provided a new method for adjusting the surface morphology of PCs by changing the cross-linking ratio of the precursor, where cross-linked polyaspartic acid was used as precursor without additional activating agents. N(2)adsorption analysis indicated that the specific surface area of the obtained PCs was as high as 1458 m(2)center dot g(-1), of which 1200 m(2)center dot g(-1)was the contribution of the microporous area and the highest pore volume was 1.13 cm(3)center dot g(-1), of which the micropore volume was 0.636 cm(3)center dot g(-1). The thermogravimetric analysis results of the precursor, and also the scanning electron microscopy and Brunauer-Emmet-Teller analysis results of the carbonization product confirmed that the prepared PCs presented multilevel pore structure, and the diameters of most pores were 0.78 and 3.97 nm; moreover, the pore size distribution was relatively uniform. This conferred the PCs the ultrahigh hydrogen adsorption capacity of up to 4.52 wt-% at 77 K and 1.13 bar, in addition to their great energy storage and catalytic potential. |
内容类型 | 期刊论文 |
源URL | [http://ir.rcees.ac.cn/handle/311016/45364] |
专题 | 大型分析仪器实验室 |
推荐引用方式 GB/T 7714 | Wei, Jun,Zhao, Jianbo,Cai, Di,et al. Synthesis of micro/meso porous carbon for ultrahigh hydrogen adsorption using cross-linked polyaspartic acid[J]. FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING,2020,14(5):857-867. |
APA | Wei, Jun,Zhao, Jianbo,Cai, Di,Ren, Wenqiang,Cao, Hui,&Tan, Tianwei.(2020).Synthesis of micro/meso porous carbon for ultrahigh hydrogen adsorption using cross-linked polyaspartic acid.FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING,14(5),857-867. |
MLA | Wei, Jun,et al."Synthesis of micro/meso porous carbon for ultrahigh hydrogen adsorption using cross-linked polyaspartic acid".FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING 14.5(2020):857-867. |
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