Animal-Derived and Plant-Derived Protein Supplement Feeds Are Important Sources of Organophosphate Esters in the Food Supply
Zhao, Nannan; Fu, Jie; Liu, Yifei; Wang, Peilong; Su, Xiaoou; Li, Xiaomin
刊名JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
2020-10-21
卷号68期号:42页码:11694-11701
关键词plant-derived protein feed animal-derived protein feed organophosphate esters flame retardants analytical methods
ISSN号0021-8561
英文摘要Animal protein supplement feeds (APFs) are important raw feed materials for livestock. APFs might be susceptible to organophosphate esters (OPEs) but have not been paid attention yet. In the present study, animal-derived (meat meal, feather meal, and blood meal) and plant-derived APFs were all found to contain detectable levels of OPEs, with 16 target OPEs ranging from 12.6 ng/g dry weight (dw) to 301 ng/g dw. Meat meal contained the highest OPE level (mean: 117 +/- 75.6 ng/g dw), followed by feather meal (54.6 +/- 30.0 ng/g dw), plant-derived feed (41.9 +/- 16.0 ng/g dw), and blood meal (28.0 +/- 12.0 ng/g dw). Considering its widespread consumption, plant-derived APFs might be an important source of OPE exposure for livestock. Dust adhesion contributed to OPE contamination both in feather meal and plant-derived APFs. Congener patterns varied among the different APFs. Tris(2-chloroisopropyl) phosphate dominated in the plant-derived feed and blood meal, while tris(2-chloroethyl) phosphate and triphenyl phosphate were the major contributors in meat meal and feather meal, respectively. Tributyl phosphate and tri-iso-butyl phosphate were found to be statistically correlated in all APFs (p < 0.01), indicating their similar behavior and common sources. The protein-associated transport pathways of OPEs need to be studied separately for different protein matrices in the future.
内容类型期刊论文
源URL[http://ir.rcees.ac.cn/handle/311016/44604]  
专题生态环境研究中心_环境化学与生态毒理学国家重点实验室
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GB/T 7714
Zhao, Nannan,Fu, Jie,Liu, Yifei,et al. Animal-Derived and Plant-Derived Protein Supplement Feeds Are Important Sources of Organophosphate Esters in the Food Supply[J]. JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY,2020,68(42):11694-11701.
APA Zhao, Nannan,Fu, Jie,Liu, Yifei,Wang, Peilong,Su, Xiaoou,&Li, Xiaomin.(2020).Animal-Derived and Plant-Derived Protein Supplement Feeds Are Important Sources of Organophosphate Esters in the Food Supply.JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY,68(42),11694-11701.
MLA Zhao, Nannan,et al."Animal-Derived and Plant-Derived Protein Supplement Feeds Are Important Sources of Organophosphate Esters in the Food Supply".JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY 68.42(2020):11694-11701.
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