Layered precursors for new zeolitic materials: Synthesis and characterization of B-RUB-39 and its condensation product B-RUB-41
Gruenewald-Lueke, Antje1; Gies, Hermann1; Mueller, Ulrich2; Yilmaz, Bilge2; Imai, H.3; Tatsumi, Takashi3; Xie, B.4; Xiao, Feng-Shou4; Bao, Xinhe5; Zhang, Weiping5
刊名microporous and mesoporous materials
2012
卷号147期号:1页码:102-109
关键词RRO framework type B-substitution Rietveld structure analysis RUB-41 Topotactic condensation of layered precursors
通讯作者antjegrunewaldluke
产权排序5,9
英文摘要condensation of layered silicate precursors leads to new, all silica zeolite frameworks. in order to introduce catalytic functionality, boron has been substituted into the silicate layer of rub-39 in a single step synthesis process. condensation of the silicate layer to the zeolite framework of rub-41. rro framework structure type, preserved b as constituent of the material. analysis of structural details obtained from rietveld analysis of powder diffraction data, (11)b and (29)si nmr experiments of the as synthesized precursor as well as of the zeolite condensation product, and crystal chemical reasoning indicates segregation of b on one specific t-site. this t-site is buried in the silicate anionic layer of the precursor shielding the additional negative charge introduced by the trivalent t-atom. (c) 2011 elsevier inc. all rights reserved.
学科主题物理化学
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary
研究领域[WOS]chemistry ; science & technology - other topics ; materials science
关键词[WOS]topotactic condensation ; silicate ; boron ; titanosilicate ; epoxidation ; nmr
收录类别SCI
语种英语
WOS记录号WOS:000295906200014
公开日期2013-10-11
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/118510]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Ruhr Univ Bochum, Inst f Geol Mineral & Geophys, D-44780 Bochum, Germany
2.BASF SE, D-67056 Ludwigshafen, Germany
3.Tokyo Inst Technol, Chem Resources Lab, Yokohama, Kanagawa 227, Japan
4.Zhejiang Univ, Dept Chem, Hangzhou 310003, Zhejiang, Peoples R China
5.Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China
6.Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, Louvain, Belgium
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Gruenewald-Lueke, Antje,Gies, Hermann,Mueller, Ulrich,et al. Layered precursors for new zeolitic materials: Synthesis and characterization of B-RUB-39 and its condensation product B-RUB-41[J]. microporous and mesoporous materials,2012,147(1):102-109.
APA Gruenewald-Lueke, Antje.,Gies, Hermann.,Mueller, Ulrich.,Yilmaz, Bilge.,Imai, H..,...&De Vos, Dirk.(2012).Layered precursors for new zeolitic materials: Synthesis and characterization of B-RUB-39 and its condensation product B-RUB-41.microporous and mesoporous materials,147(1),102-109.
MLA Gruenewald-Lueke, Antje,et al."Layered precursors for new zeolitic materials: Synthesis and characterization of B-RUB-39 and its condensation product B-RUB-41".microporous and mesoporous materials 147.1(2012):102-109.
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