Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose

	Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose
	Li, Guangyi 1,2; Li, Ning 1; Wang, Zhiqiang 1,3; Li, Changzhi 1; Wang, Aiqin 1; Wang, Xiaodong 1; Cong, Yu 1; Zhang, Tao 1
刊名	chemsuschem
	2012
卷号	5 期号:10 页码:1958-1966
关键词	renewable resources zirconium heterogeneous catalysis platinum biomass
通讯作者	张涛
产权排序	1,1
英文摘要	hydroxyalkylationalkylation (haa) coupled with hydrodeoxygenation is a promising route for the synthesis of renewable high-quality diesel or jet fuel. in this work, a series of solid-acid catalysts were firstly used for haa between lignocellulose-derived furan and carbonyl compounds. among the investigated catalysts, nafion-212 resin demonstrated the highest activity and stability. owing to the high activity of the reactants and the advantage in industrial integration, the haa of 2-methylfuran (2-mf) and furfural can be considered as a prospective route in future applications. catalyst loading, reaction temperature, and time had evident effects on the haa of 2-mf and furfural over nafion-212 resin. finally, the haa product of 2-mf and furfural was hydrogenated over a pd/c catalyst and hydrodeoxygenated over pt-loaded solid-acid catalysts. pt/zirconium phosphate (pt/zrp) was found to be the best catalyst for hydrodeoxygenation. over the 4?% pt/zrp catalyst, a 94?% carbon yield of diesel and 75?% carbon yield of c15 hydrocarbons (with 6-butylundecane as the major component) was achieved.
学科主题	物理化学
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	mesoporous sba-15 silica ; high-surface-area ; catalytic conversion ; aldol-condensation ; liquid fuels ; oxygenated hydrocarbons ; transportation fuels ; gamma-valerolactone ; ethylene-glycol ; bond formation
收录类别	SCI
语种	英语
WOS记录号	WOS:000310074200012
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/118126]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China 3.Sichuan Univ, Dept Chem Engn, Chengdu 610065, Peoples R China
推荐引用方式 GB/T 7714	Li, Guangyi,Li, Ning,Wang, Zhiqiang,et al. Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose[J]. chemsuschem,2012,5(10):1958-1966.
APA	Li, Guangyi.,Li, Ning.,Wang, Zhiqiang.,Li, Changzhi.,Wang, Aiqin.,...&Zhang, Tao.(2012).Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose.chemsuschem,5(10),1958-1966.
MLA	Li, Guangyi,et al."Synthesis of High-Quality Diesel with Furfural and 2-Methylfuran from Hemicellulose".chemsuschem 5.10(2012):1958-1966.