Production of singlet oxygen by the reaction of non-basic hydrogen peroxide with chlorine gas

	Production of singlet oxygen by the reaction of non-basic hydrogen peroxide with chlorine gas
	Tian, Wenming; Shi, Wenbo; Yang, Heping; Cui, Rongrong; Deng, Liezheng
刊名	physical chemistry chemical physics
	2012
卷号	14 期号:38 页码:13344-13349
ISSN号	1463-9076
通讯作者	邓列征
产权排序	1,1
英文摘要	non-basic hydrogen peroxide was found to be very easy to react with cl-2 to produce singlet oxygen o-2(a(1) delta(g)) (i.e. the molecular oxygen in its first electronic excited state) when an h+ absorbent such as c5h5n, ch3coonh4, hcoonh4 or nh4f was added into h2o2 aqueous solution, and the long concealed fact that molecular h2o2 can react with cl-2 to produce o-2(a(1) delta(g)) was then uncovered. it is only when an h+ absorbent has provided a stronger base than h2o to absorb the h+ produced during the reaction that o-2(a(1) delta(g)) can be produced.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical ; physics, atomic, molecular & chemical
研究领域[WOS]	chemistry ; physics
关键词[WOS]	molecular-oxygen ; hypochlorite ; acidification ; spectroscopy ; oxidation ; mechanism ; dynamics ; laser ; water
收录类别	SCI
语种	英语
WOS记录号	WOS:000308826000028
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/117725]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning Provin, Peoples R China
推荐引用方式 GB/T 7714	Tian, Wenming,Shi, Wenbo,Yang, Heping,et al. Production of singlet oxygen by the reaction of non-basic hydrogen peroxide with chlorine gas[J]. physical chemistry chemical physics,2012,14(38):13344-13349.
APA	Tian, Wenming,Shi, Wenbo,Yang, Heping,Cui, Rongrong,&Deng, Liezheng.(2012).Production of singlet oxygen by the reaction of non-basic hydrogen peroxide with chlorine gas.physical chemistry chemical physics,14(38),13344-13349.
MLA	Tian, Wenming,et al."Production of singlet oxygen by the reaction of non-basic hydrogen peroxide with chlorine gas".physical chemistry chemical physics 14.38(2012):13344-13349.