Recent advances in preparation and application of hybrid organic-silica monolithic capillary columns

	Recent advances in preparation and application of hybrid organic-silica monolithic capillary columns
	Ou, Junjie 1; Lin, Hui 1,2; Zhang, Zhenbin 1,2; Huang, Guang 1,3; Dong, Jing 1; Zou, Hanfa 1
刊名	electrophoresis
	2013
卷号	34 期号:1 页码:126-140
关键词	Monolithic columns Organic-silica hybrid materials Ring-opening polymerization Sol-gel
ISSN号	0173-0835
通讯作者	欧俊杰
产权排序	1,1
英文摘要	hybrid organic-silica monolithic columns, regarded as a second generation of silica-based monoliths, have received much interest due to their unique properties over the pure silica-based monoliths. this review mainly focuses on development in the fields of preparation of hybrid monolithic columns in a capillary and their application for cec and capillary liquid chromatography separation, as well as for sample pretreatment of solid-phase microextraction and immobilized enzyme reactor since july 2010. the preparation approaches are comprehensively summarized with three routes: (i) general solgel process using trialkoxysilanes and tetraalkoxysilanes as coprecursors; (ii) one-pot process of alkoxysilanes and organic monomers concomitantly proceeding solgel chemistry and free radical polymerization; and (iii) other polymerization approaches of organic monomers containing silanes. the modification of hybrid monoliths containing reactive groups to acquire the desired surface functionality is also described.
学科主题	物理化学
WOS标题词	science & technology ; life sciences & biomedicine ; physical sciences
类目[WOS]	biochemical research methods ; chemistry, analytical
研究领域[WOS]	biochemistry & molecular biology ; chemistry
关键词[WOS]	performance liquid-chromatography ; opening metathesis polymerization ; molecularly imprinted polymer ; plasma-mass spectrometry ; less common applications ; one-pot approach ; sol-gel method ; stationary phases ; reversed-phase ; click chemistry
收录类别	SCI
语种	英语
WOS记录号	WOS:000313123100011
公开日期	2013-10-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/117615]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatog R&A Ctr, CAS Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China 3.Dalian Univ Technol, Dalian, Peoples R China
推荐引用方式 GB/T 7714	Ou, Junjie,Lin, Hui,Zhang, Zhenbin,et al. Recent advances in preparation and application of hybrid organic-silica monolithic capillary columns[J]. electrophoresis,2013,34(1):126-140.
APA	Ou, Junjie,Lin, Hui,Zhang, Zhenbin,Huang, Guang,Dong, Jing,&Zou, Hanfa.(2013).Recent advances in preparation and application of hybrid organic-silica monolithic capillary columns.electrophoresis,34(1),126-140.
MLA	Ou, Junjie,et al."Recent advances in preparation and application of hybrid organic-silica monolithic capillary columns".electrophoresis 34.1(2013):126-140.