Homogeneous and heterogeneous catalysts for hydrogenation of CO2 to methanol under mild conditions

doi:10.1039/d0cs01331e

	Homogeneous and heterogeneous catalysts for hydrogenation of CO2 to methanol under mild conditions
	Bai, Shao-Tao 2; De Smet, Gilles 3; Liao, Yuhe 1,2; Sun, Ruiyan 2; Zhou, Cheng 2; Beller, Matthias 4; Maes, Bert U. W.3; Sels, Bert F.2
刊名	CHEMICAL SOCIETY REVIEWS
	2021-04-07
卷号	50 期号:7 页码:4259-4298
ISSN号	0306-0012
DOI	10.1039/d0cs01331e
通讯作者	Beller, Matthias(Matthias.Beller@catalysis.de) ; Maes, Bert U. W.(bert.maes@uantwerpen.be) ; Sels, Bert F.(bert.sels@kuleuven.be)
英文摘要	In the context of a carbon neutral economy, catalytic CO2 hydrogenation to methanol is one crucial technology for CO2 mitigation providing solutions for manufacturing future fuels, chemicals, and materials. However, most of the presently known catalyst systems are used at temperatures over 220 degrees C, which limits the theoretical yield of methanol production due to the exothermic nature of this transformation. In this review, we summarize state-of-the-art catalysts, focusing on the rationales behind, for CO2 hydrogenation to methanol at temperatures lower than 170 degrees C. Both hydrogenation with homogeneous and heterogeneous catalysts is covered. Typically, additives (alcohols, amines or aminoalcohols) are used to transform CO2 into intermediates, which can further be reduced into methanol. In the first part, molecular catalysts are discussed, organized into: (1) monofunctional, (2) M/NH bifunctional, and (3) aromatization-dearomatization bifunctional molecular catalysts. In the second part, heterogeneous catalysts are elaborated, organized into: (1) metal/metal or metal/support, (2) active-site/N or active-site/OH bifunctional heterogeneous catalysts, and (3) cooperation of catalysts and additives in a tandem process via crucial intermediates. Although many insights have been gained in this transformation, in particular for molecular catalysts, the mechanisms in the presence of heterogeneous catalysts remain descriptive and insights unclear.
资助项目	Federal Excellence of Science (EoS) call of FWO/FNRS (BIOFACT)[30902231] ; European Research Council (ERC)[NoNaCat 670986] ; KU Leuven ; special research fund BOF UAntwerpen
WOS关键词	METAL-LIGAND COOPERATION ; TETRADENTATE BIPYRIDINE LIGANDS ; LOW-TEMPERATURE HYDROGENATION ; CARBON-DIOXIDE ; ASYMMETRIC HYDROGENATION ; CARBOXYLIC-ACIDS ; FORMIC-ACID ; NONCOVALENT INTERACTIONS ; SEQUENTIAL HYDROGENATION ; 5-CO-ORDINATE COMPLEXES
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000639924700015
资助机构	Federal Excellence of Science (EoS) call of FWO/FNRS (BIOFACT) ; European Research Council (ERC) ; KU Leuven ; special research fund BOF UAntwerpen
内容类型	期刊论文
源URL	[http://ir.giec.ac.cn/handle/344007/33175]
专题	中国科学院广州能源研究所
通讯作者	Beller, Matthias; Maes, Bert U. W.; Sels, Bert F.
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Katholieke Univ Leuven, Ctr Sustainable Catalysis & Engn, Celestijnenlaan 200F, B-3001 Heverlee, Belgium 3.Univ Antwerp, Dept Chem, Div Organ Synth, Groenenborgerlaan 171, B-2020 Antwerp, Belgium 4.Leibniz Inst Catalysis, Albert Einstein Str 29a, Rostock, Germany
推荐引用方式 GB/T 7714	Bai, Shao-Tao,De Smet, Gilles,Liao, Yuhe,et al. Homogeneous and heterogeneous catalysts for hydrogenation of CO2 to methanol under mild conditions[J]. CHEMICAL SOCIETY REVIEWS,2021,50(7):4259-4298.
APA	Bai, Shao-Tao.,De Smet, Gilles.,Liao, Yuhe.,Sun, Ruiyan.,Zhou, Cheng.,...&Sels, Bert F..(2021).Homogeneous and heterogeneous catalysts for hydrogenation of CO2 to methanol under mild conditions.CHEMICAL SOCIETY REVIEWS,50(7),4259-4298.
MLA	Bai, Shao-Tao,et al."Homogeneous and heterogeneous catalysts for hydrogenation of CO2 to methanol under mild conditions".CHEMICAL SOCIETY REVIEWS 50.7(2021):4259-4298.