Self-assembly of 1D FeSe2 chains and Fe(dien)(2) complexes for ferrimagnetic inorganic-organic hybrid cuboids

doi:10.1016/j.jmmm.2021.168585

	Self-assembly of 1D FeSe2 chains and Fe(dien)(2) complexes for ferrimagnetic inorganic-organic hybrid cuboids
	Pan, Desheng 1; Kuang, Qifeng 1; Tong, Peng 2; Tong, Wei 3; Fan, Liubing 4; Zhao, Jing 4; Li, Da 1; Choi, Chuljin 5; Zhang, Zhidong 1
刊名	JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
	2022-01-15
卷号	542
关键词	Inorganic-organic hybrids Self-assembly Magnetic property Electron spin resonance
ISSN号	0304-8853
DOI	10.1016/j.jmmm.2021.168585
通讯作者	Li, Da(dali@imr.ac.cn)
英文摘要	Challenges still remain in producing room-temperature ferromagnetism/ferrimagnetism in inorganic-organic hybrid compounds. Here, we report the Fe vacancy-doped inorganic-organic (FexSe(2))(2)Fe(dien)(2) (dien = diethylenetriamine, x = 0.86) hybrid cuboids by self-assemble of finite one-dimensional (1D) FeSe2 chains and Fe (dien)(2) complexes. A growth model is proposed by kinetically controllable syntheses of novel Fe2x+1Se4(dien)(2) hybrids. The Rietveld refinement reveals that Fe vacancies in the Fe2.71Se4(dien)(2) hybrid cuboids induce large distortions of the FeSe2 chains and the room-temperature lattice parameters are a = 9.225(4) angstrom, b = 18.021(8) angstrom and c = 11.609(6) angstrom. Magnetic measurements and electron spin resonance spectra of the Fe2.71Se4(dien)(2) hybrid cuboids show the ferrimagnetism with the Curie temperature (T-C) of 600 K and the spin glass state with the freezing temperature (T-f) of 108 K. Impressive room-temperature ferrimagnetic properties of the Fe2.71Se4(dien)(2) hybrid cuboids were ascribed to the high concentration of Fe3+ vacancies (0.29 per cell) in the hybrid cuboids, which is supported by the Fe-57 Mossbauer spectrum fitting based on the ferrimagnetic model.
资助项目	National Natural Science Foundation of China[51971221] ; National Natural Science Foundation of China[52031014] ; National Natural Science Foundation of China[U1732275] ; Beijing Natural Science Foundation[2182080] ; National Key R&D Program of China[2017YFA0206302] ; National Key R&D Program of China[2017YFA0700702] ; National Key R&D Program of China[2017YFA0403502] ; Ministry of Science and Technology of China ; Future Materials Discovery Program through the National Research Foundation of Korea (NRF) - Ministry of Science and technology and ICT[2016M3D1A1027835]
WOS关键词	MAGNETIC-PROPERTIES ; SUPERCONDUCTIVITY ; ORDER
WOS研究方向	Materials Science ; Physics
语种	英语
出版者	ELSEVIER
WOS记录号	WOS:000705023900012
资助机构	National Natural Science Foundation of China ; Beijing Natural Science Foundation ; National Key R&D Program of China ; Ministry of Science and Technology of China ; Future Materials Discovery Program through the National Research Foundation of Korea (NRF) - Ministry of Science and technology and ICT
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/125543]
专题	中国科学院合肥物质科学研究院
通讯作者	Li, Da
作者单位	1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China 3.Chinese Acad Sci, Anhui Prov Key Lab Condensed Matter Phys Extreme, High Magnet Field Lab, Hefei 230031, Anhui, Peoples R China 4.Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing Municipal Key Lab New Energy Mat & Techno, Beijing 100083, Peoples R China 5.Korea Inst Mat Sci, 797 Changwondaero, Chang Won 51508, Gyeongnam, South Korea
推荐引用方式 GB/T 7714	Pan, Desheng,Kuang, Qifeng,Tong, Peng,et al. Self-assembly of 1D FeSe2 chains and Fe(dien)(2) complexes for ferrimagnetic inorganic-organic hybrid cuboids[J]. JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS,2022,542.
APA	Pan, Desheng.,Kuang, Qifeng.,Tong, Peng.,Tong, Wei.,Fan, Liubing.,...&Zhang, Zhidong.(2022).Self-assembly of 1D FeSe2 chains and Fe(dien)(2) complexes for ferrimagnetic inorganic-organic hybrid cuboids.JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS,542.
MLA	Pan, Desheng,et al."Self-assembly of 1D FeSe2 chains and Fe(dien)(2) complexes for ferrimagnetic inorganic-organic hybrid cuboids".JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS 542(2022).