Plasmon-enhanced dye-sensitized solar cells through porphyrin-silver nanoparticle hybrid structures: Experimental and computational studies

doi:10.1016/j.jpowsour.2021.230407

	Plasmon-enhanced dye-sensitized solar cells through porphyrin-silver nanoparticle hybrid structures: Experimental and computational studies
	Ghadari, Rahim 1; Sabri, Alireza 1; Saei, Paria-Sadat 1; Kong, Fantai 2; Mohammadzadeh, Yousef 1; Guzel, Emre 3
刊名	JOURNAL OF POWER SOURCES
	2021-11-01
卷号	511
关键词	Plasmonic effect Dye-sensitized solar cells Silver nanoparticles Porphyrin
ISSN号	0378-7753
DOI	10.1016/j.jpowsour.2021.230407
通讯作者	Ghadari, Rahim(r-ghadari@tabrizu.ac.ir)
英文摘要	Surface plasmon resonance of silver nanoparticles (Ag NPs) was used to improve light absorption of porphyrins in plasmon-enhanced porphyrin-sensitized solar cells (PSSCs). Porphyrins with different substituents consisting -H, -Me, -MeO, -F, -Cl, -Br, -CO2H, -SO3H, -NO2, and -NH2 were used to study the effect of the interactions between photoactive dye molecules and plasmonic Ag NPs on the performance of PSSCs. The obtained results revealed that zinc tetra(4-carboxyphenyl)porphyrin and zinc tetra(4-aminophenyl)porphyrin have made the biggest impact on the performance of plasmon-enhanced PSSCs. Computational studies were done to study the electronic properties of porphyrin molecules with electron-withdrawing and electron-donating substituents interacted with Ag NPs. The theoretical studies confirmed that the electronic nature of substituents of porphyrins has a considerable effect on the electronic properties of porphyrin-AgNPs systems. In continue, Ag@ZIF-8 coreshell NPs were prepared to overcome the challenge of corrosion of Ag plasmonic nanoparticles. The results showed that using porphyrin-Ag@ZIF-8 systems, in many cases, the performance of PSSCs is increased relative to corresponding porphyrins but is decreased relative to porphyrin-AgNPs systems.
资助项目	CAS-Iranian Vice Presidency for Sci-ence and Technology Joint Research Project[96003452] ; research council of University of Tabriz
WOS关键词	OPEN-CIRCUIT VOLTAGE ; PHOTOVOLTAIC PERFORMANCE ; CHARGE RECOMBINATION ; METAL ; CONVERSION ; PHOTOANODE ; ENERGY ; LIGHT ; PHOTOCURRENT ; SUNLIGHT
WOS研究方向	Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science
语种	英语
出版者	ELSEVIER
WOS记录号	WOS:000697030300001
资助机构	CAS-Iranian Vice Presidency for Sci-ence and Technology Joint Research Project ; research council of University of Tabriz
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/125343]
专题	中国科学院合肥物质科学研究院
通讯作者	Ghadari, Rahim
作者单位	1.Univ Tabriz, Fac Chem, Dept Organ & Biochem, Tabriz 5166616471, Iran 2.Chinese Acad Sci, Inst Appl Technol, Hefei Inst Phys Sci, Key Lab Photovolta & Energy Conservat Mat, Hefei 230088, Peoples R China 3.Sakarya Univ Appl Sci, Dept Engn Fundamental Sci, Fac Technol, TR-54050 Sakarya, Turkey
推荐引用方式 GB/T 7714	Ghadari, Rahim,Sabri, Alireza,Saei, Paria-Sadat,et al. Plasmon-enhanced dye-sensitized solar cells through porphyrin-silver nanoparticle hybrid structures: Experimental and computational studies[J]. JOURNAL OF POWER SOURCES,2021,511.
APA	Ghadari, Rahim,Sabri, Alireza,Saei, Paria-Sadat,Kong, Fantai,Mohammadzadeh, Yousef,&Guzel, Emre.(2021).Plasmon-enhanced dye-sensitized solar cells through porphyrin-silver nanoparticle hybrid structures: Experimental and computational studies.JOURNAL OF POWER SOURCES,511.
MLA	Ghadari, Rahim,et al."Plasmon-enhanced dye-sensitized solar cells through porphyrin-silver nanoparticle hybrid structures: Experimental and computational studies".JOURNAL OF POWER SOURCES 511(2021).