A thermal stable fluorescent coordination polymer for sensing nitro aromatic compounds and metal ions with high selectivity and sensitivity in aqueous media

doi:10.1016/j.optmat.2021.111327

	A thermal stable fluorescent coordination polymer for sensing nitro aromatic compounds and metal ions with high selectivity and sensitivity in aqueous media
	Nartey, Kojo Aboagye 1; Wang, Xiaoyu 1,2; Zhang, Jing 1; Hu, Jinsong 1,2
刊名	OPTICAL MATERIALS
	2021-09-01
卷号	119
关键词	Coordination polymer Crystal structure Nitro aromatic compounds Luminescent sensing
ISSN号	0925-3467
DOI	10.1016/j.optmat.2021.111327
通讯作者	Nartey, Kojo Aboagye(Kojochem@126.com) ; Hu, Jinsong(jshu@aust.edu.cn)
英文摘要	A new mixed ligand coordination polymer [Cd3(5-NH2-mdc)3(Bipy)3 center dot H2O]n has been synthesized under solvothermal reactions of Cd(NO3)2 center dot 4H2O, Oxalylbis (azanediyl) diisophthalic acid and 2, 2 '-biprydyl to produce a complex 1. The as-synthesized MOF show pi center dot center dot center dot pi interactions of benzene rings between adjacent chains, which further expands its structure from a 1D to 3D network by various pi center dot center dot center dot pi interactions and H-bondings, these weak interactions give the complex 1 enhanced stability. Photoluminescent experiments show that the complex 1 exhibits sensitive and selective detections of TNP, Pb2+ and Fe3+, the luminescent sensing performance was also preliminary tested in physiological solution. The detection mechanisms of the complex 1 were also further investigated by both experimentations and calculations.
资助项目	Natural Science Foundation of China[21671004] ; Outstanding Youth Funding of Anhui Province[1908085J10]
WOS关键词	ORGANIC FRAMEWORK ; LUMINESCENT SENSOR ; HEAVY-METALS ; FE3+ IONS ; 2,4,6-TRINITROPHENOL ; WATER ; ADSORPTION ; EXPLOSIVES ; LIGAND ; ANIONS
WOS研究方向	Materials Science ; Optics
语种	英语
出版者	ELSEVIER
WOS记录号	WOS:000684547800007
资助机构	Natural Science Foundation of China ; Outstanding Youth Funding of Anhui Province
内容类型	期刊论文
源URL	[http://ir.hfcas.ac.cn:8080/handle/334002/124278]
专题	中国科学院合肥物质科学研究院
通讯作者	Nartey, Kojo Aboagye; Hu, Jinsong
作者单位	1.Anhui Univ Sci & Technol, Sch Chem Engn, State Key Lab Min Response & Disaster Prevent & C, Huainan 232001, Peoples R China 2.Chinese Acad Sci, Key Lab Photovolta & Energy Conservat Mat, Hefei Inst Phys Sci, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Nartey, Kojo Aboagye,Wang, Xiaoyu,Zhang, Jing,et al. A thermal stable fluorescent coordination polymer for sensing nitro aromatic compounds and metal ions with high selectivity and sensitivity in aqueous media[J]. OPTICAL MATERIALS,2021,119.
APA	Nartey, Kojo Aboagye,Wang, Xiaoyu,Zhang, Jing,&Hu, Jinsong.(2021).A thermal stable fluorescent coordination polymer for sensing nitro aromatic compounds and metal ions with high selectivity and sensitivity in aqueous media.OPTICAL MATERIALS,119.
MLA	Nartey, Kojo Aboagye,et al."A thermal stable fluorescent coordination polymer for sensing nitro aromatic compounds and metal ions with high selectivity and sensitivity in aqueous media".OPTICAL MATERIALS 119(2021).