Cyanogel and its derived-materials: properties, preparation methods, and electrochemical applications | |
Lin, Shi-Yi1; Yao, You-Qiang2; Zhang, Lu1; Feng, Jiu-Ju1; Wang, Ai-Jun1 | |
刊名 | MATERIALS TODAY ENERGY |
2021-06-01 | |
卷号 | 20 |
关键词 | Inorganic hydrogel Three-dimensional soft template Porous framework Electrocatalytic reactions Energy-related devices |
ISSN号 | 2468-6069 |
DOI | 10.1016/j.mtener.2021.100701 |
通讯作者 | Zhang, Lu(zhanglu@zjnu.edu.cn) ; Wang, Ai-Jun(ajwang@zjnu.cn) |
英文摘要 | Cyanogel, a novel inorganic polymeric hydrogel, is constituted by chlorometallates and transition-metal cyanometallates, which is thought as fascinating and promising precursor to produce highly alloyed materials with stereochemical structures. In this review, the properties, synthesis methods, and electrochemical applications of the cyanogel and its derivates are systematically discussed. With intrinsic properties such as 3D interconnected backbones, uniform distributions of metals at atomic level, and porous structures, the cyanogel-derived materials exhibit superior activities and stabilities. During the synthesis process, the skeleton of cyanogel serves as soft template for generating metal structures without any surfactant. Due to the versatility and tunability of cyanogels, their derivatives not only provide foreseeable opportunities for preparation of highly efficient nanomaterials in electrocatalytic reactions, but also broaden their practical applications in energy-related devices such as fuel cells, water splitting electrolyzers, metal-air batteries, energy storage batteries, and supercapacitors. Through this review, we aim to provide valuable guidelines for constructing highly effective materials in practice. (C) 2021 Elsevier Ltd. All rights reserved. |
资助项目 | National Natural Science Foundation of China[21805245] ; Natural Science Foundation of Zhejiang Province[LQ20E030004] |
WOS关键词 | CARBON-NITRIDE ELECTROCATALYSTS ; SUPERIOR OXYGEN EVOLUTION ; METAL-ORGANIC FRAMEWORK ; TERNARY ALLOY NETWORK ; METHANOL FUEL-CELLS ; HYDROGEN EVOLUTION ; FACILE SYNTHESIS ; ENHANCED ACTIVITY ; PD-CO ; BIFUNCTIONAL ELECTROCATALYST |
WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
语种 | 英语 |
出版者 | ELSEVIER SCI LTD |
WOS记录号 | WOS:000659520500003 |
资助机构 | National Natural Science Foundation of China ; Natural Science Foundation of Zhejiang Province |
内容类型 | 期刊论文 |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/123832] |
专题 | 中国科学院合肥物质科学研究院 |
通讯作者 | Zhang, Lu; Wang, Ai-Jun |
作者单位 | 1.Zhejiang Normal Univ, Coll Chem & Life Sci, Minist Educ Adv Catalysis Mat, Key Lab,Coll Geog & Environm Sci, Jinhua 321004, Zhejiang, Peoples R China 2.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Inst Adv Mfg Technol, Ningbo 315201, Peoples R China |
推荐引用方式 GB/T 7714 | Lin, Shi-Yi,Yao, You-Qiang,Zhang, Lu,et al. Cyanogel and its derived-materials: properties, preparation methods, and electrochemical applications[J]. MATERIALS TODAY ENERGY,2021,20. |
APA | Lin, Shi-Yi,Yao, You-Qiang,Zhang, Lu,Feng, Jiu-Ju,&Wang, Ai-Jun.(2021).Cyanogel and its derived-materials: properties, preparation methods, and electrochemical applications.MATERIALS TODAY ENERGY,20. |
MLA | Lin, Shi-Yi,et al."Cyanogel and its derived-materials: properties, preparation methods, and electrochemical applications".MATERIALS TODAY ENERGY 20(2021). |
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