Anisotropy engineering of metal organic framework derivatives for effective electromagnetic wave absorption | |
Liu, Guang2; Wu, Chen2; Lei, Hu2; Xin, Hu1; Zhang, Xuefeng1; Tang, Jin3; Du, Haifeng3; Wang, Xinhua2; Yan, Mi2 | |
刊名 | CARBON |
2021-08-30 | |
卷号 | 181 |
关键词 | Anisotropy engineering Self-assembly MOF derivatives Electromagnetic wave absorption |
ISSN号 | 0008-6223 |
DOI | 10.1016/j.carbon.2021.05.015 |
通讯作者 | Wu, Chen(chen_wu@zju.edu.cn) ; Zhang, Xuefeng(zhang@hdu.edu.cn) ; Yan, Mi(mse_yanmi@zju.edu.cn) |
英文摘要 | Anisotropy engineering serves as an effective method to achieve unique properties and enhanced performance of materials. Here MOF-71 and derivatives with tuned anisotropy have been achieved via facial tuning the proticity of the solvents, giving rise to nanoflake assemblies into bellows-, boat-and flowerlike microstructures. Three anisotropy dimensions including Faceting, Aspect ratio and Arrangement have been proposed to describe the anisotropy of the assemblies, which are further evaluated by heterotype (H), flatness (F) and orderliness (O). Combined off-axis electron holography and electromagnetic scattered field simulation visualize uniform distribution of magnetic lines due to enhanced anisotropy of the bellows-like derivatives. This gives rise to strengthened magnetic loss and electromagnetic wave absorption for the anisotropy evolution from the flower-, boat-to bellows-like structure. As such the work not only provides versatile strategy for anisotropy engineering and reification of the anisotropy for complicated assembled structures, but also insights on impacts of the anisotropy on the distribution of stray field, magnetic dipoles and scattered field for the design of electromagnetic absorbers, which are extendable to various areas including but not limited to magnetics, electrics and optics. (c) 2021 Elsevier Ltd. All rights reserved. |
资助项目 | Key Research and Development Program of Zhejiang Province[2020C05014] ; Key Research and Development Program of Zhejiang Province[2020C01008] ; Ningbo Major Special Projects of the Plan Science and Technology Innovation 2025[2018B10085] |
WOS关键词 | MICROWAVE-ABSORPTION ; JANUS PARTICLES ; EFFICIENT ; SURFACE ; NANOPARTICLES |
WOS研究方向 | Chemistry ; Materials Science |
语种 | 英语 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
WOS记录号 | WOS:000661678100006 |
资助机构 | Key Research and Development Program of Zhejiang Province ; Ningbo Major Special Projects of the Plan Science and Technology Innovation 2025 |
内容类型 | 期刊论文 |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/123805] |
专题 | 中国科学院合肥物质科学研究院 |
通讯作者 | Wu, Chen; Zhang, Xuefeng; Yan, Mi |
作者单位 | 1.Hangzhou Dianzi Univ, Sch Mat & Environm Engn, Hangzhou 310018, Peoples R China 2.Zhejiang Univ, State Key Lab Silicon Mat, Sch Mat Sci & Engn, Hangzhou 310027, Peoples R China 3.Chinese Acad Sci, High Field Magnet Lab, Anhui Prov Key Lab Condensed Matter Phys Extreme, Hefei 230031, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Guang,Wu, Chen,Lei, Hu,et al. Anisotropy engineering of metal organic framework derivatives for effective electromagnetic wave absorption[J]. CARBON,2021,181. |
APA | Liu, Guang.,Wu, Chen.,Lei, Hu.,Xin, Hu.,Zhang, Xuefeng.,...&Yan, Mi.(2021).Anisotropy engineering of metal organic framework derivatives for effective electromagnetic wave absorption.CARBON,181. |
MLA | Liu, Guang,et al."Anisotropy engineering of metal organic framework derivatives for effective electromagnetic wave absorption".CARBON 181(2021). |
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