Oxidation of petroleum-based byproducts diformyltricyclodecanes (DFTD) with O-2 under catalyst-free and ultra-low temperature

doi:10.1016/j.cjche.2019.04.012

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 省部共建新疆特有药用资源利用重点实验室

	Oxidation of petroleum-based byproducts diformyltricyclodecanes (DFTD) with O-2 under catalyst-free and ultra-low temperature
	Zhang, LB (Zhang, Libo)[ 1 ]; Xing, BW (Xing, Bowen)[ 1 ]; Deng, BL (Deng, Bailian)[ 1 ]; Wang, TF (Wang, Tianfu)[ 2 ]; Ming, H (Ming, Hui)[ 1 ]
刊名	CHINESE JOURNAL OF CHEMICAL ENGINEERING
	2020
卷号	28 期号:1 页码:266-270
关键词	Diforinyltricyclodecanes Oxidation Catalyst-free Solvent Oxidative route
ISSN号	1004-9541
DOI	10.1016/j.cjche.2019.04.012
英文摘要	Oxidation of petroleum-based byproduct dicyclopentadiene derived diformyltricyclodecanes (DFTD) to dicarboxyltridodecanesacids (DCTDA) was conducted under catalyst-free and ultra-low temperature conditions with O-2 as oxidant. In the perspective of industry process, oxygen pressure and contents, solvent and raw material initial concentrations were screened to evaluate their influence on DCTDA generation. Results indicate that DFTD oxidation can occur rather easily under no-catalyst and ultra-low temperature conditions with O-2 as oxidant. Oxygen content and pressure had positive effect on DCTDA production, gamma-valerolactone (GVL) behaved best on DFTD generation in dynamics, while methanol could be used as a protective solvent to preserve DITD. Besides, the existence of water in solvent was not beneficial to DCTDA production because of poor DFTD compatibility with water. The mechanisms of O-2 and solvent influence on DCTDA generation were discussed. Meanwhile, the oxidation route of DFTD-Intermediate-DCTDA was proposed. The present work exhibits the valued potential of DFTD, which will have a positive effect on high added value of petroleum based by-products. (C) 2019 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd
WOS记录号	WOS:000519533600030
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/7302]
专题	新疆理化技术研究所_省部共建新疆特有药用资源利用重点实验室
作者单位	1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Plant Resources & Chem Arid Zone, Urumqi 830011, Peoples R China 2.China Univ Petr Beijing Karamay, Coll Engn, State Key Lab Heavy Oil Proc, Karamay 834000, Peoples R China
推荐引用方式 GB/T 7714	Zhang, LB ,Xing, BW ,Deng, BL ,et al. Oxidation of petroleum-based byproducts diformyltricyclodecanes (DFTD) with O-2 under catalyst-free and ultra-low temperature[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2020,28(1):266-270.
APA	Zhang, LB ,Xing, BW ,Deng, BL ,Wang, TF ,&Ming, H .(2020).Oxidation of petroleum-based byproducts diformyltricyclodecanes (DFTD) with O-2 under catalyst-free and ultra-low temperature.CHINESE JOURNAL OF CHEMICAL ENGINEERING,28(1),266-270.
MLA	Zhang, LB ,et al."Oxidation of petroleum-based byproducts diformyltricyclodecanes (DFTD) with O-2 under catalyst-free and ultra-low temperature".CHINESE JOURNAL OF CHEMICAL ENGINEERING 28.1(2020):266-270.