SrTi(IO3)(6)center dot 2H(2)O and SrSn(IO3)(6): distinct arrangements of lone pair electrons leading to large birefringences | |
Liu, KT (Liu, Kaitong)[ 1,2 ]; Han, J (Han, Jian)[ 1 ]; Huang, JB (Huang, Junben)[ 1 ]; Wei, ZL (Wei, Zhonglei)[ 1,2 ]; Yang, ZH (Yang, Zhihua)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ] | |
刊名 | RSC ADVANCES |
2021 | |
卷号 | 11期号:17页码:10309-10315 |
ISSN号 | 2046-2069 |
DOI | 10.1039/d0ra10726c |
英文摘要 | Three new iodates SrTi(IO3)(6)center dot 2H(2)O, (H3O)(2)Ti(IO3)(6), and SrSn(IO3)(6) have been synthesized via a facile hydrothermal method. The three compounds have zero-dimensional crystal structures composed of one [MO6](8-) (M = Ti, Sn) octahedron connected with six [IO3](-) trigonal pyramids. However, the particular coordination of Sr2+ cations results in distinct arrangements of lone pair electrons in an [IO3](-) trigonal pyramid, which leads to large birefringences. More importantly, this work enriches the species crystal chemistry for [M(IO3)(6)](2-) (M = Ti, Sn) clusters-containing iodates. |
WOS记录号 | WOS:000629707400055 |
内容类型 | 期刊论文 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/7803] |
专题 | 新疆理化技术研究所_材料物理与化学研究室 |
通讯作者 | Han, J (Han, Jian)[ 1 ]; Pan, SL (Pan, Shilie)[ 1 ] |
作者单位 | 1.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, KT ,Han, J ,Huang, JB ,et al. SrTi(IO3)(6)center dot 2H(2)O and SrSn(IO3)(6): distinct arrangements of lone pair electrons leading to large birefringences[J]. RSC ADVANCES,2021,11(17):10309-10315. |
APA | Liu, KT ,Han, J ,Huang, JB ,Wei, ZL ,Yang, ZH ,&Pan, SL .(2021).SrTi(IO3)(6)center dot 2H(2)O and SrSn(IO3)(6): distinct arrangements of lone pair electrons leading to large birefringences.RSC ADVANCES,11(17),10309-10315. |
MLA | Liu, KT ,et al."SrTi(IO3)(6)center dot 2H(2)O and SrSn(IO3)(6): distinct arrangements of lone pair electrons leading to large birefringences".RSC ADVANCES 11.17(2021):10309-10315. |
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