Al-8(BO3)(4)(B2O5)F-8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B-O Groups

doi:10.1021/acs.inorgchem.9b03067

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 材料物理与化学研究室

	Al-8(BO3)(4)(B2O5)F-8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B-O Groups
	Wang, Y (Wang, Ya)[ 1,2 ]; Han, J (Han, Jian)[ 1,2 ]; Huang, JB (Huang, Junben)[ 1 ]; Yang, ZH (Yang, Zhihua)[ 1,2 ]; Pan, SL (Pan, Shilie)[ 1,2 ]
刊名	INORGANIC CHEMISTRY
	2020
卷号	59 期号:1 页码:810-817
ISSN号	0020-1669
DOI	10.1021/acs.inorgchem.9b03067
英文摘要	Al-8(BO3)(4)(B2O5)F-8, as a new aluminum borate fluoride, has been synthesized by the high-temperature reaction with the closed system for the first time. With respect to its structure, the isolated BO3 and B2O5 groups reside in the center and edge of tunnels constructed by the AlO4F2 polyhedra. The AlO4F2 polyhedra play the vital role on the formation of isolated B-O groups. According to our investigation, Al-8(BO3)(4)(B2O5)F-8 is the first case, which features two types of independently isolated B-O groups in the aluminum borate fluorides. Its cutoff edge is up to deep ultraviolet (DUV) range. What is more, the energy dispersive spectroscopy (EDS), infrared (IR) spectrum, and the first-principles calculations of Al-8(BO3)(4)(B2O5)F-8 have been performed.
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/7238]
专题	新疆理化技术研究所_材料物理与化学研究室
通讯作者	Pan, SL (Pan, Shilie)[ 1,2 ]
作者单位	1.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, CAS Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
推荐引用方式 GB/T 7714	Wang, Y ,Han, J ,Huang, JB ,et al. Al-8(BO3)(4)(B2O5)F-8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B-O Groups[J]. INORGANIC CHEMISTRY,2020,59(1):810-817.
APA	Wang, Y ,Han, J ,Huang, JB ,Yang, ZH ,&Pan, SL .(2020).Al-8(BO3)(4)(B2O5)F-8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B-O Groups.INORGANIC CHEMISTRY,59(1),810-817.
MLA	Wang, Y ,et al."Al-8(BO3)(4)(B2O5)F-8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B-O Groups".INORGANIC CHEMISTRY 59.1(2020):810-817.